Halide perovskite quantum dots (QDs) have great potential in photocatalytic applications if their low charge transportation efficiency and chemical instability can be overcome. To circumvent these obstacles, we anchored CsPbBr QDs (CPB) on NH -rich porous g-C N nanosheets (PCN) to construct the composite photocatalysts via N-Br chemical bonding. The 20 CPB-PCN (20 wt % of QDs) photocatalyst exhibits good stability and an outstanding yield of 149 μmol h g in acetonitrile/water for photocatalytic reduction of CO to CO under visible light irradiation, which is around 15 times higher than that of CsPbBr QDs. This study opens up new possibilities of using halide perovskite QDs for photocatalytic application.
Functionalized reduced graphene oxide (FRGO) wrapped with a phosphorus and nitrogen-containing flame retardant (FR) was successfully prepared via a simple one-pot method and well characterized.
Arrays of mesoporous manganese dioxide, mp-MnO(2), nanowires were electrodeposited on glass and silicon surfaces using the lithographically patterned nanowire electrodeposition (LPNE) method. The electrodeposition procedure involved the application, in a Mn(ClO(4))(2)-containing aqueous electrolyte, of a sequence of 0.60 V (vs MSE) voltage pulses delineated by 25 s rest intervals. This "multipulse" deposition program produced mp-MnO(2) nanowires with a total porosity of 43-56%. Transmission electron microscopy revealed the presence within these nanowires of a network of 3-5 nm diameter fibrils that were X-ray and electron amorphous, consistent with the measured porosity values. mp-MnO(2) nanowires were rectangular in cross-section with adjustable height, ranging from 21 to 63 nm, and adjustable width ranging from 200 to 600 nm. Arrays of 20 nm × 400 nm mp-MnO(2) nanowires were characterized by a specific capacitance, C(sp), of 923 ± 24 F/g at 5 mV/s and 484 ± 15 F/g at 100 mV/s. These C(sp) values reflected true hybrid electrical energy storage with significant contributions from double-layer capacitance and noninsertion pseudocapacitance (38% for 20 nm × 400 nm nanowires at 5 mV/s) coupled with a Faradaic insertion capacity (62%). These two contributions to the total C(sp) were deconvoluted as a function of the potential scan rate.
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