Polycyclic aromatic hydrocarbons (PAHs) concentrations were analysed in the organic film on the glass surfaces of different functional areas in central Shanghai. Concentration levels of total PAHs in the organic film ranged from 1,348.5 to 4,007.9 ng m(-2). The concentration of PAHs was lowest in parks and green spaces (1,348.5 ng m(-2)) and highest in traffic zones (4,007.9 ng m(-2)). A concentration gradient of total PAHs was observed as follows: traffic zones > commercial areas > cultural and educational areas > parks and green spaces. The distribution of PAHs was characterised by 3-4 ring PAHs in the study areas. The most abundant PAHs were phenanthrene (20.5 %), fluorene (16.7 %), pyrene (12.4 %) and chrysene (Chry) (11.2 %). The mass of the bulk film was composed of organic and inorganic compounds and ranged from 246 to 1,288 mg m(-2). The bulk film thickness varied from 144 to 757 nm in the different functional areas. The ratios of An/178 and Fl/202 and principal component analysis suggested that PAHs came mainly from the mixed sources of fossil fuel, coal and incomplete combustion of biomass. Benzo[a]anthracene (BaA)/Chry is not suitable for use as a tracer for the transmission process of PAHs because of the rapid depletion of BaA in the organic film by photooxidation during daylight hours. The concentration of benzo[a]pyrene equivalent (BaPeq) varied from 21 to 701 ng g(-1), and the major carcinogenic contributors of the 16 PAHs were BaP, DahA, B[b/k]F and InP, accounting for 83 % of BaPeq.
Taking the frame-supported shear wall structure of a 102.1 m high metro depot as the test object, the structure has obvious vertical irregularity, and a quasi-static test was carried out on the structural model with the scale of 1/5. The damage development and strain of the structure were observed by applying displacement loads under different seismic actions, and the experimental phenomena and measured data were analyzed. The results show that the safety performance of the structure meets the seismic requirements of the MCE (Maximum considered earthquake) condition. Under the action of load, a reasonable damage mechanism is formed in which the components above the transfer story crack first and those below the transfer story crack later, which is in line with the design concept of “the performance objective of the bottom frame structure is higher than that of the upper shear wall structure”. The transfer plate is mainly subjected to shear deformation, the possible shear failure of the transfer plate should be avoided by reasonable design. Due to the large height difference between the first floor and the second floor, the structure may be adversely affected, so it is necessary to make the yielding floor appear in the bottom strengthening part above the transfer story. Under the SLE (Service level earthquake) and DBE (Design based earthquake) conditions, the bottom frame of the structure is mainly subjected to elastic deformation. Under the MCE (Maximum considered earthquake) condition, the bottom frame of the structure causes a lot of damage, increases energy consumption and decreases stiffness, which further proves that “the performance goal of the bottom frame structure is higher than that of the upper shear wall structure”.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.