Graphene, a two-dimensional (2D) carbon nanomaterial, has attracted worldwide attention owing to its fascinating properties. One of critical bottlenecks on some important classes of applications, such as printed electronics, conductive coatings, and composite fillers, is the lack of industrial-scale methods to produce high-quality graphene in the form of liquid suspensions, inks, or dispersions. Since 2008, when liquid-phase exfoliation (LPE) of graphene via sonication was initiated, huge progress has been made in the past decade. This review highlights the latest progress on the successful preparation of graphene in various media, including organic solvents, ionic liquids, water/polymer or surfactant solutions, and some other green dispersants. The techniques of LPE, namely sonication, high-shear mixing, and microfluidization are reviewed subsequently. Moreover, several typical devices of high-shear mixing and exfoliation mechanisms are introduced in detail. Finally, we give perspectives on future research directions for the development of green exfoliation media and efficient techniques for producing high-quality graphene. This systematic exploratory study of LPE will potentially pave the way for the scalable production of graphene, which can be also applied to produce other 2D layered materials, such as BN, MoS2, WS2, etc.

In order to investigate the turbulent drag reduction phenomenon and understand its mechanism, direct numerical simulation (DNS) was carried out on decaying homogeneous isotropic turbulence (DHIT) with and without polymer additives. We explored the polymer effect on DHIT from the energetic viewpoint, i.e. the decay of the total turbulent kinetic energy and energy distribution at each scale in Fourier space and from the phenomenological viewpoint, i.e. the alterations of vortex structures, the enstrophy and the strain. It was obtained that in DHIT with polymer additives the decay of the turbulent kinetic energy is faster than that in the Newtonian fluid case and a modification of the turbulent kinetic energy transfer process for the Newtonian fluid flow is observed due to the release of the polymer elastic energy into flow structures at certain small scales. Besides, we deduced the transport equations of the enstrophy and the strain, respectively, for DHIT with polymer additives. Based on the analyses of these transport equations, it was found that polymer additives depress both the enstrophy and the strain in DHIT as compared to the Newtonian fluid case, indicating the inhibition effect on small-scale vortex structures and turbulence intensity by polymers.

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Turbulent drag reduction of 30 ppm cetyltrimethyl ammonium chloride (CTAC) solution flow in a channel was investigated with particle image velocimetry (PIV) combining with proper orthogonal decomposition (POD). Measurements were made at inlet fluid temperature of 304 K and at Reynolds number 2.5×104 (based on the channel height, bulk velocity, and solvent viscosity) for both water and CTAC solution flows with 70.0% drag reduction rate. The two-component velocity fields in the streamwise-wall normal plane were recorded by PIV. In order to study the characteristics of turbulent drag-reducing channel flow, POD was performed to identify the near-wall coherent structures based on PIV-measured data. POD is a powerful low-dimensional analysis tool that can be used to identify coherent structures embedded in the turbulent shear flow. We mainly studied a comparison between the first dominant POD eigenmodes of water and drag-reducing CTAC solution flows. Coherent structures were seen as the sum of several eigenmodes that possess a dominant energy of the flow, say 90%. It was obtained that the amount of eigenmodes required for capturing the coherent structures was 233 and 195 for water and CTAC solution flows, respectively, which means the decrease in the complexity in CTAC solution flow. Based on the analysis of POD eigenmodes of water and CTAC solution flows, we captured the processes that can reflect the ejection motion of low-speed fluid from the wall and sweep motion of high-speed fluid toward the wall associating with turbulent bursting events. The results showed that CTAC additives can inhibit the turbulent bursting processes (both strength and occurrence frequency), resulting in a great decrease in turbulent contribution to frictional drag and drag reduction, which is sufficient to understand deeply the mechanism of turbulent drag reduction.