Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.
Producing electrolytes with high ionic conductivity has been a critical challenge in the progressive development of solid oxide fuel cells (SOFCs) for practical applications. The conventional methodology uses the ion doping method to develop electrolyte materials, e.g., samarium-doped ceria (SDC) and yttrium-stabilized zirconia (YSZ), but challenges remain. In the present work, we introduce a logical design of non-stoichiometric CeO 2-δ based on non-doped ceria with a focus on the surface properties of the particles. The CeO 2−δ reached an ionic conductivity of 0.1 S/cm and was used as the electrolyte in a fuel cell, resulting in a remarkable power output of 660 mW/cm 2 at 550°C. Scanning transmission electron microscopy (STEM) combined with electron energy-loss spectroscopy (EELS) clearly clarified that a surface buried layer on the order of a few nanometers was composed of Ce 3+ on ceria particles to form a CeO 2−δ @CeO 2 core-shell heterostructure. The oxygen deficient layer on the surface provided ionic transport pathways. Simultaneously, band energy alignment is proposed to address the short circuiting issue. This work provides a simple and feasible methodology beyond common structural (bulk) doping to produce sufficient ionic conductivity. This work also demonstrates a new approach to progress from material fundamentals to an advanced lowtemperature SOFC technology.
Group 10 metal catalysts have shown much promise for the copolymerization of nonpolar with polar alkenes to directly generate functional materials, but access to high copolymer molecular weights nevertheless remains a key challenge toward practical applications in this field. In the context of identifying new strategies for molecular weight control, we report a series of highly polarized P(V)-P(III) chelating ligands that manifest unique space filling and electrostatic effects within the coordination sphere of single component Pd polymerization catalysts and exert important influences on (co)polymer molecular weights. Single component, cationic phosphonic diamide-phosphine (PDAP) Pd catalysts are competent to generate linear, functional polyethylenes with M up to ca. 2 × 10 g mol, significantly higher than prototypical catalysts in this field, and with polar content up to ca. 9 mol %. Functional groups are positioned by these catalysts almost exclusively along the main chain, not at chain ends or ends of branches, which mimics the microstructures of commercial linear low-density polyethylenes. Spectroscopic, X-ray crystallographic, and computational data indicate PDAP coordination to Pd manifests cationic yet electron-rich active species, which may correlate to their complementary catalytic properties versus privileged catalysts such as electrophilic α-diimine (Brookhart-type) or neutral phosphine-sulfonato (Drent-type) complexes. Though steric blocking within the catalyst coordination sphere has long been a reliable strategy for catalyst molecular weight control, data from this study suggest electronic control should be considered as a complementary concept less prone to suppression of comonomer enchainment that can occur with highly sterically congested catalysts.
Nanosized, yet ordered: Active and selective Pd2Ga intermetallic compounds supported on carbon nanotubes have been synthesized and applied to alkyne hydrogenation. Intermetallic compounds on the nanoscale are necessary to achieve high mass activity, whereas ordered structures within intermetallic compounds form high barriers for subsurface chemistry and prevent large active ensembles on Pd surface.
Sufficiently high oxygen ion conductivity of electrolyte is critical for good performance of low-temperature solid oxide fuel cells (LT-SOFCs). Notably, material conductivity, reliability, and manufacturing cost are the major barriers hindering LT-SOFC commercialization. Generally, surface properties control the physical and chemical functionalities of materials. Hereby, we report a Sm, Pr, and Nd triple-doped ceria, exhibiting the highest ionic conductivity among reported doped-ceria oxides, 0.125 S cm at 600 °C. It was designed using a two-step wet-chemical coprecipitation method to realize a desired doping for Sm at the bulk and Pr/Nd at surface domains (abbreviated as PNSDC). The redox couple Pr/Pr contributes to the extraordinary ionic conductivity. Moreover, the mechanism for ionic conductivity enhancement is demonstrated. The above findings reveal that a joint bulk and surface doping methodology for ceria is a feasible approach to develop new oxide-ion conductors with high impacts on advanced LT-SOFCs.
Supported catalysts are widely studied, and exploring new promising supports is significant to access more applications. In this work, novel copper-containing MOR-type zeolites Cu-MOR were synthesized in a one-pot template-free route and served as efficient supports for vanadium oxide. In the heterogeneous oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) with molecular oxygen (O2) under ambient pressure, the obtained catalyst demonstrated high yield (91.5%) and good reusability. Even under the ambient air pressure, it gave a DFF yield of 72.1%. Structure-activity relationship analysis indicated that the strong interaction between the framework Cu species and the guest V sites accounted for the remarkable performance. This work reveals that the Cu-MOR zeolite uniquely acts as the robust support toward well-performed non-noble metal heterogeneous catalyst for biomass conversion.
Although one of the most promising aqueous batteries, all Zn‐Mn systems suffer from Zn dendrites and the low‐capacity Mn4+/Mn3+ process (readily leading to the occurrence of Jahn–Teller distortion, which in turn causes structural collapse and voltage/capacity fading). Here, the Mn3+ reconstruction and disproportionation are exploited to prepare the stable, Mn2+‐rich manganese oxides on carbon‐cloth (CMOs) in a discharged state through an inverted design, which promotes reversible Mn2+/Mn4+ kinetics and mitigates oxygen‐related redox activity. Such a 1.65 V Mn2+‐rich cathode enable constructing a 2.2 V Zn‐Mn battery, providing a high area capacity of 4.16 mA h cm–2 (25 mA h cm–2 for 10 mL electrolyte) and superior 4000‐cycle stability. Moreover, a flexible hybrid 2.7 V Zn‐Mn battery is constructed using 2‐pH hydrogel electrolytes to demonstrate excellent practicality and stability. A further insight has been gained to the commercial application of aqueous energy storage devices toward low‐cost, high safety, and excellent energy density.
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