Directional solution coating by the Chinese brush provides a facile approach to fabricate highly oriented polymer thin films by finely controlling the wetting and dewetting processes under directional stress. The biggest advantage of the Chinese brush over the normal western brush is the freshly emergent hairs used, whose unique tapered structure renders a dynamic balance of the liquid within the brush by multiple forces when interacting with the liquid. Consequently, the liquid is steadily held within the brush without any unexpected leakage, making the liquid transfer proceed in a well-controllable manner. It is demonstrated that the Chinese brush coating enables the crystallization of the polymer and the self-assembly of conjugated backbones to proceed in a quasi-steady state via a certain direction, which is attributed to the controllable receding of the three-phase contact line during the dewetting process by the multiple parallel freshly emergent hairs. The as-prepared polymer thin films exhibit over six times higher charge-carrier mobility compared to the spin-coated films, which therefore provides a general approach for high-performance organic thin-film transistors.
D–A conjugated
molecules are complicated in both their molecular
and their packing structures. In this perspective, we summarize more
than 40 crystal lattices of conjugated oligomers to identify the morphological
influence of each building block on the D–A molecules. These
lattice structures reveal not only the packing preferences of the
conjugated oligomers but also the conformational disorder in the lattices.
The presence of this disorder in slowly grown crystals implies that
attaining total long-range conformational order is challenging for
D–A oligomers, which are structurally complicated and readily
distorted and which have building blocks of incommensurate packing
dimensions. In optoelectronic applications, a decreased duration of
processing can prevent ordering and trap the thin films of D–A
oligomers from becoming crystalline phases. Although D–A oligomers
conform to packing principles in the formation of a single crystal,
their phase behaviors in the formation of active thin films are much
more difficult to comprehend. Continuous advances in methods of characterization
are still strongly required for the steps of attaining a true structure–property
relation of D–A oligomers in active films for optoelectronic
applications.
Herein, we suggest a unique approach to control the handedness of twisted lamellae in banded spherulites of a stereoregular polymer, isotactic poly(2-vinylpyridine) (iP2VP). When (R)- or (S)-hexahydromandelic acid (HMA), which can associate with iP2VP, was introduced as a chiral dopant, mirror-image CD spectra in the complex systems showed induced circular dichroism (ICD) of the iP2VP by chiral HMA. Banded spherulites resulting from lamellar twisting due to the imbalanced stresses at the opposite folding surfaces could be formed by crystallization of the iP2VP/HMA complexes, which had a crystalline structure similar to that of neat iP2VP. A preferential sense of the twisted crystalline lamellae was found in the iP2VP/HMA complex, thus suggesting homochiral evolution from conformational to hierarchical chirality.
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