The article deals with the experimental and numerical thermal-flow behaviours of a low-temperature Phase Change Material (PCM) used in Thermal Energy Storage (TES) industrial applications. The investigated PCM is a composition that consists of a mixture of paraffin wax capsuled in a melamine-formaldehyde membrane and water, for which a phase change process occurs within the temperature range of 4 °C to 6 °C and the maximum heat storage capacity is equal to 72 kJ/kg. To test the TES capabilities of the PCM for operating conditions close to real ones, a series of experimental tests were performed on cylindrical modules with fixed heights of 250 mm and different outer diameters of 15, 22, and 28 mm, respectively. The module was tested in a specially designed wind tunnel where the Reynolds numbers of between 15,250 to 52,750 were achieved. In addition, a mathematical model of the analysed processes, based on the enthalpy porosity method, was proposed and validated. The temperature changes during the phase transitions that were obtained from the numerical analyses in comparison with the experimental results have not exceeded 20% of the relative error for the phase change region and no more than 10% for the rest. Additionally, the PCM was examined while using a Scanning Electron Microscope (SEM), which indicated no changes in the internal structure during phase transitions and a homogeneous structure, regardless of the tested temperature ranges.
The inclusions in large diamond single crystals have effects on its ultimate performance, which restricts its industrial applications to a great extent. Therefore, it is necessary to study the inclusions systematically. In this paper, large diamond single crystals with different content values of inclusions are synthesized along the (100) surface by the temperature gradient method (TGM) under 5.6 GPa at different temperatures. With the synthetic temperature changing from 1200 • C to 1270 • C, the shapes of diamonds change from plate to low tower, to high tower, even to steeple. From the microscopic photographs of the diamond samples, it can be observed that with the shapes of the samples changing at different temperatures, the content values of inclusions in diamonds become zero, a little, much and most, correspondingly. Consequently, with the temperature growing from low to high, the content values of inclusions in crystals increase. The origin of inclusions is explained by the difference in growth rate between diamond crystal and its surface. The content values of inclusions in diamond samples are quantitatively calculated by testing the densities of diamond samples. And the composition and inclusion content are analyzed by energy dispersive spectroscopy (EDS) and x-ray diffraction (XRD). From contrasting scanning electron microscopy (SEM) photographs, it can be found that the more the inclusions in diamond, the more imperfect the diamond surface is.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.