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Based on the results of the National Oil Shale Resource Evaluation in China conducted from 2003 to 2006, and combined with the new exploration progress in recent years, the characteristics and resource potential of oil shale in China have been systematically studied in this paper. Oil shale resources in China are abundant, with deposits mainly found in the continental environment and, secondarily, in marine-continental facies. The color of oil shale is black to grayish black, black to gray brown or gray to dark gray. In general, the darker the color, the higher the quality of oil shale. The most common minerals in oil shale are clay minerals, quartz and feldspars. The concentration of organic carbon in Chinese oil shale is high, between 7.48 and 38.02%. By organic genetic type, oil shale can be divided into sapropelic, humosapropelic and saprohumic oil shale. Oil shale used for industrial purposes has a medium to high oil yield and high ash content. Oil shale resources in China are mainly concentrated in 20 provinces and autonomous regions, 50 basins and 83 petroliferous shale areas. Total oil shale resources are estimated at approximately 978 billion tons, i.e. about 61 billion tons of in-place shale oil, mainly distributed throughout eastern and central China and the Qinghai-Tibet Region in western China. This paper outlines the distribution of oil shale deposits in China with respect to depositional basin type, and oil shale age and grade. Oil shale in China was deposited mainly in extensional and intra-plate basins during the Mesozoic and the Cenozoic. The size of the basins diminishes from older to younger deposits. Oil shale resources that yield shale oil more than 5% by weight account for about 72% of the rock's total resources in the country.

The separation and recovery of uranium from radioactive wastewater is important from the standpoints of environmental protection and uranium reuse. In the present work, magnetically collectable TiO 2 /Fe 3 O 4 and its graphene composites were fabricated and utilized for the photocatalytical removal of U(VI) from aqueous solutions. It was found that, under ultraviolet (UV) irradiation, the photoreactivity of TiO 2 /Fe 3 O 4 for the reduction of U(VI) was 19.3 times higher than that of pure TiO 2 , which is strongly correlated with the Fe 0 and additional Fe(II) generated from the reduction of Fe 3 O 4 by TiO 2 photoelectrons. The effects of initial uranium concentration, solution pH, ionic strength, the composition of wastewater, and organic pollutants on the U(VI) removal by TiO 2 /Fe 3 O 4 were systematically investigated. The results demonstrated its excellent performance in the cleanup of uranium contamination. As graphene can efficiently attract the TiO 2 photoelectrons and thus decrease their transfer to Fe 3 O 4 , the photodissolution of Fe 3 O 4 in the TiO 2 /graphene/Fe 3 O 4 composite can be largely alleviated compared to that of the TiO 2 /Fe 3 O 4 , rendering this ternary composite a much higher stability. In addition, scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray absorption near edge spectroscopy (XANES), and X-ray photoelectron spectroscopy (XPS) were used to explore the reaction mechanisms.

Thorium separation has recently become a hot topic because of the potential application of thorium as a future nuclear fuel, while metal-organic framework (MOF) materials have received much attention in the separation field due to their unique properties. Herein, a highly porous and stable MOF, UiO-66, and its carboxyl derivatives (UiO-66-COOH and UiO-66-(COOH)) were synthesized and explored for the first time for Th(IV) capture from a weak acidic solution. Although the introduction of carboxyl groups into UiO-66 leads to an obvious decrease in the surface area and pore volume, the adsorbability toward Th(IV) is greatly enhanced. At pH = 3.0, the saturated sorption capacity for Th(IV) into UiO-66-(COOH) reached 350 mg/g, representing one of the largest values for Th(IV) capture by solid extraction. Moreover, the functionalized MOFs show fast sorption kinetics and desirable selectivity toward Th(IV) over a range of competing metal ions. A possible mechanism for the selective recognition of Th(IV) by these MOFs was explored on the basis of extended X-ray absorption fine structure and Fourier transform infrared analysis. It is concluded that UiO-66-COOH and UiO-66-(COOH) sorb Th(IV) through the coordination of carboxyl anions in the pores of the MOFs, whereas in the case of UiO-66, both the precipitation and the exchange with the organic solvent contribute to the Th(IV) uptake. This study contributes to the assessment of the feasibility of MOFs applied in actinides separation and better understanding of actinides sorption behavior in this kind of hybrid porous solid materials.