Determining the total structure of metal nanoparticles is vital to understand their properties. In this work, the first all-alkynyl-protected Ag nanocluster, Ag(C≡CPh), was synthesized and structurally characterized by single crystal diffraction. Ag atoms are arranged in a Ag@Ag@Ag three shell structure and all 44 phenylethynyl ligands coordinated with Ag in a μ mode. In spite of being absent in nanocluster, P NMR study reveals that bidentate phosphine first reacts with Ag(I) to form a dinuclear complex, from which Ag atoms are then released to phenylethynyl ligands. This phosphine mediated strategy may find general application in synthesis of alkynyl-protected Ag nanoclusters.
At present, the energy structure of China is shifting towards cleaner and lower amounts of carbon fuel, driven by environmental needs and technological advances. Nuclear energy, which is one of the major low-carbon resources, plays a key role in China's clean energy development. To formulate appropriate energy policies, it is necessary to conduct reliable forecasts. This paper discusses the nuclear energy consumption of China by means of a novel fractional grey model FAGMO(1,1,k). The fractional accumulated generating matrix is introduced to analyse the fractional grey model properties. Thereafter, the modelling procedures of the FAGMO(1,1,k) are presented in detail, along with the transforms of its optimal parameters. A stochastic testing scheme is provided to validate the accuracy and properties of the optimal parameters of the FAGMO (1,1,k). Finally, this model is used to forecast China's nuclear energy consumption and the results demonstrate that the FAGMO(1,1,k) model provides accurate prediction, outperforming other grey models.
Remanufacturing has received extensive attention due to its advantages in material and energy saving, emission reduction and is often considered a viable approach for the realization of a circular economy. Remanufacturing ecological performance reflects the ability of an enterprise to balance economic and environmental benefits. Therefore, evaluating the remanufacturing ecological performance is of great significance for leveraging the benefits of remanufacturing and promoting the concept of sustainability and the implementation of a circular economy in the industry. To this end, a set of data-driven techniques, i.e., data envelopment analysis, R clustering and grey relational analysis, are deployed to analyze and evaluate the ecological performance of a remanufacturing process. The effectiveness and feasibility of the proposed method are illustrated via a case study of remanufacturing for hydraulic cylinder and boom cylinder. Furthermore, a number of critical factors, e.g., energy-saving rate, remanufacturing process cost and rate of remanufacturing, for end-of-life products have been identified as the key drivers impacting the remanufacturing ecological performance. So as to improve remanufacturing ecological performance, optimizing production technology, implementing lean remanufacturing and raising public acceptability over remanufacturing products are effective measures. The research results of the present work can provide support for remanufacturing enterprises to guide and improve their ecological performance and formulate better development strategies.
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