The objective of this study is to investigate the effect of operating conditions on palm oil mill effluent (POME) using activated sludge treatment. The operating conditions examined are initial pH, hydraulic retention time (HRT), organic loading rate (OLR), initial mixed liquor volatile suspended solids (MLVSS), solid retention time (SRT), and molasses concentration added as a carbon source. The efficiency of activated sludge was evaluated by treating the anaerobic treated POME under aerobic conditions based on the F/M ratio of 0.3 kg BOD/kg MLVSS.day. The best operating condition for initial pH, HRT, OLR, initial MLVSS, SRT, and molasses concentration were found to be 6.5 ± 0.1, 48 hours, 650 ± 20 mg/L, 2000 ± 200 mg/L, 10 days and 50 mg/L, respectively. However, the removal of chemical oxygen demand (COD) and biochemical oxygen demand (BOD) in POME ranging from 62 -68% and 60 -65% respectively for all best conditions. In fact, the removal of BOD still does not meet the Department of Environment (DOE)'s discharge standard limit of 20 mg/L. Therefore, further investigation and study of POME treatment need to be carried out in order to find a better solution to meet the DOE discharge standard.
Kinetic parameter is a basis for design and optimization of activated sludge POME treatment. In fact, most of the kinetic parameter value used in design and optimization are default values taken from municipal wastewater. The kinetic parameters for POME treatment have not been thoroughlystudied and most of the system is using the Activated Sludge Models (ASM), either in modelling or design. Thus, the kinetic study of POME treatment by activated sludge system were carried out to obtain the kinetic parameters for the POME treatment plant design calculation.In this study, POME treatment was carriedout in batch studiesinto 14 L aeration tank with activated sludge for the biological oxidation process with optimum pH at 6.5 ± 0.1, MLVSS of 2000 ± 200 mg/Lfor HRT of 48 h and feeding with 650 ± 20 mg BOD3/L of anaerobic treated POME, while SRT was controlled at a range of 10 days to 20 days with interval of 2 days for the kinetic study experiment. From this kinetic study, the kinetic parameters for COD and BOD basis had been determined for maximum yields coefficient (Y), endogenous decay coefficient (kd), maximum specific substrate utilization rate (k) and half-velocity constant (Ks) at 0.2369 mg VSS/mg COD, 0.1060 day-1, 2.2717 day 1 and 758.7705 mg/L for COD basis whilst the kinetic parameters value for BOD basis were 0.6718 mg VSS/mg BOD3, 0.0658 day-1, 1.4136 day-1 and 556.1526 mg/L, respectively. Since the BOD is one of the discharge parameters in discharge regulatory, thus kinetic parameters for BOD basis will be used for the system design of POME treatment.
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