Conventional binders cannot meet the current performance requirements of asphaltic pavements due to increase in traffic volumes and loads. Nanomaterials, due to their exceptional mechanical properties, are gaining popularity as bitumen modifiers to enhance the performance properties of the asphaltic concrete. Carbon Nanotubes (CNTs) are one of the most widely used nanomaterials because of their strength properties, light weight, small size, and large surface area. CNT addition results in improved substrate characteristics as compared to other modifiers. Due to high length to diameter ratio, dispersion of CNTs in bitumen is a complex phenomenon. In this study, dispersion of CNTs in bitumen was carried out using both dry and wet mixing techniques, the latter was selected on the basis of homogeneity of the resultant asphalt mixture. Scanning Electron Microscopy (SEM) was used to check the dispersion of CNTs in binder while Fourier Transform Infrared Spectroscopy (FTIR) was carried out to ensure the removal of solvent used for wet mixing. Conventional bitumen tests (penetration, softening point, and ductility), dynamic shear rheometer tests, rolling bottle tests, and bitumen bond strength tests were employed to check the improvement in the rheological and adhesion properties of bitumen while wheel tracker test was used to check the improvement in resistance against permanent deformation of asphalt mixtures after addition of CNTs. Results show that CNTs improved the higher temperature performance and permanent deformation resistance in both binder and mixtures. Improvement in bitumen–aggregate adhesion properties and moisture resistance was also observed.

Asphalt is one of the primary materials that are extensively used by the pavement industry throughout the world. Its behaviour is highly dependent on the amount of loading and the level of temperature it is exposed to. Asphalt has been modified in the past with different additives to improve its high- or low-temperature properties. In Pakistan, temperature remains high for most of the time of the year; hence, asphalt binders with less susceptibility to higher temperatures are preferred for flexible pavements. Acids, polymers, fibers, and extenders have been used by the researchers to improve high-temperature performance of asphalt mixture. In the present study, a bio material derived from the animal waste, named as bone glue (BG), has been used with the 60/70 penetration grade binder in dosages of 3%, 6%, 9%, and 12% by weight of asphalt binder. The bone glue is produced from a sustainable source. It is a cost-effective and eco-friendly material. Moreover, it produces a durable and nonhazardous asphalt composite. The influence of addition of bone glue on asphalt binder was evaluated using different testing techniques which include consistency tests, rheological analysis, and adhesion tests. Furthermore, different performance tests were conducted on bone glue-modified asphalt mixtures. Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis were carried out to ensure the homogeneity and proper mixing of bone glue in asphalt binder. The results from the tests reveal that bone glue stiffens the asphalt binder hence enhancing its high temperature performance. Bone glue dosage of 9% by weight of the binder was found to be the optimum dosage based on the rheological and performance analysis.

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Nano-technology has played a vital role in upgrading the durability and sustainability of asphalt pavements during the last decade. Conventional bitumen does not provide adequate performance against permanent deformation in severe weather conditions. Quartz nano-size particles (QNPs) (1, 3, and 5% by weight of the bitumen) were employed in this research to modify the conventional base bitumen PG 58–16. Conventional physical (penetration, softening, ductility, and flash and fire point), rheological, frequency sweep, high-performance grading, and moisture susceptibility tests were performed to investigate the enhancement of the base bitumen performance. Marshall mix design was conducted on each asphalt mixture to determine the optimum bitumen content (OBC) percentage for the preparation of wheel tracker samples to evaluate the effect of QNPs on asphalt mixtures. Laboratory test findings showed that the optimum concentration of QNPs is 5% by weight of base bitumen. The homogeneity and proper stable dispersion of QNPs in the bitumen were validated via scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and storage stability tests. At higher temperatures, the QNP-modified asphalt mixtures exhibited higher stiffness, stripping resistance, and rutting potential. It was concluded that QNPs effectively upgrade durability and permanent deformation resistance at high temperatures and, therefore, the sustainability of asphalt roads.