Rice-crab culture is the characteristic rice ecological breeding model used in the Panjin area of Liaohe River Basin, China, and it can improve the ecological environment and create increased economic benefits. From a food perspective, both rice yield and quality, which are closely related to the fertilization mode, should be considered. However, the effect of different fertilization modes on rice quality has not been comprehensively investigated in this coculture system. This study investigated the effects of three fertilization modes(FP1, FP2, and OPT) divided according to different fertilization types and methods on rice yield and quality, and set up a non-fertilized control group. In the rice-crab culture system, FP2 used fewer fertilizers and had a lower economic cost, and the yield was only slightly less than that of OPT(highest yield) but there was no statistical difference. FP2 elicited the best appearance quality and better cooking and eating quality among all treatment modes. Compared with CK, three fertilization modes significantly increased the protein content in rice and decreased the amylose content, which would lead to the deterioration of rice eating quality. However FP2 had the least protein increase and the least amylose reduction. There was no significant change in crude fat and starch content. Therefore, the FP2 fertilization mode was the best choice for the rice-crab culture system, as it significantly improved rice yield and increased rice quality at a relatively low cost.

In this study, switchable hydrophilic solvent‐based dispersive liquid‐liquid microextraction coupled with high‐performance liquid chromatography was developed for the determination of four sulfonylurea herbicides in soils. For the first time, the sample pretreatment was achieved due to the similar acid‐base status of sulfonylurea herbicides and switchable hydrophilic solvent. In the extraction step, sulfonylurea herbicides were extracted as anions and transferred to an alkaline solution with switchable hydrophilic solvent anions. In the concentration step, two types of anions were transformed to their molecular state after the aqueous solution was acidified. In addition, the dispersion and microextraction processes were completed efficiently with the simultaneous formation of analytes and extractants. The factors affecting the extraction performance were optimized. Under the optimized conditions, good linearity was observed for each herbicide with correlation coefficients ranging from 0.9952 to 0.9978. The limits of detection were in the range of 0.1–0.2 μg/g. Moreover, the relative recoveries of the sulfonylurea herbicides at spiking levels of 0.5, 1, and 1.5 μg/g in soil samples were between 75 and 111% (relative standard deviations: 0.4–11.4%). Therefore, the proposed method in this study could be successfully applied to the analysis of four types of sulfonylurea herbicides in soil samples.

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Global warming brings extreme climate, triggers forest fire and water resources scarcity and more natural disaster, threats the survival and development of human and other global organisms seriously, and causes each country to realize the importance of climate governance to improve the cooperation of climate governance. Focusing on several issues in global climate governance as well as international treaties of current climate change in China as research object of climate change legislation, proposing international treaties with optimizing climate governance, establishing regulatory law enforcement system in climate change as an approach to complete global climate governance and providing Chinese plan of global climate governance from the perspective of Chinese domestic climate change legislation is going to be raising.

A type of dispersive solid-phase extraction based on magnetic biosorbents was developed.

A novel effervescent tablet-assisted switchable hydrophilicity solvent-based on-site dispersive liquid-liquid microextraction coupled with gas chromatography detection has been developed to determine five pyrethroid insecticides in environmental water samples. In this method, effervescent tablets contain effervescent precursors and extractants, which play a dual role of dispersion and extraction. After effervescence reaction, the formation of extractant and the extraction of analytes were accomplished simultaneously. Phase separation were carried by filtration using homemade filter column, which of filter is oil-absorbing cotton polypropylene. After phase separation, the extractant phase were obtained by elution. No electric instrument was required in sample pre-treatment step in the developed method. Experimental conditions affecting the extraction efficiencies have been optimized, such as type and amount of extractant, type of effervescent tablets, etc. Under the optimized conditions, the linearity was 5-500μg L-1, with coefficients greater than 0.9990. The limit of detection and the limit of quantitation were in the range of 0.22-1.88μg L-1 and 0.75-6.25μg L-1. The relative standard deviations ranged from 0.8% to 6.1%. The enrichment factors were in the range of 65-108. This method was successfully applied to the on-site processing of tap, reservoir and river water.

DOI: https://doi.org/10.1002/jssc.202100703 The cover picture shows a novel method for the determination of four types of sulfonylurea herbicides in soils by switchable hydrophilic solvent‐based dispersive liquid‐liquid microextraction coupled with high‐performance liquid chromatography. Switchable hydrophilic solvent became an excellent extractant in sulfonylurea herbicide analysis due to the unique connection between the switchable hydrophilic solvent and the sulfonylurea herbicides. Therefore, the proposed method was proved to be green, more benign to the environment and easy to operate and had a potential to be applied to other complex samples.