Solvent vapour annealed (SVA) technique was successfully used in controlling the morphology of polymer thin film blending with low molecular weight chromophoric (LMWC) molecules.
Nonlinear absorption (NLA) of hydrogenated nanocrystalline silicon (nc-Si:H) has been investigated through the open aperture Z-scan method for the photon energy of the incident irradiance slightly less than the bandgap of the sample. NLA responses have been observed to be highly sensitive to the wavelength and intensity of the incident irradiance as well as to the bandgap of the sample, indicating greatly tunable NLA of nc-Si:H. The band tail of nc-Si:H appears to play a crucial role in such NLA responses.
Nonlinear refraction (NLR) of hydrogenated nanocrystalline silicon (nc-Si:H) has been investigated through the close aperture Z-scan method. We demonstrate a significant NLR and a unique feature of controllable NLR characteristics between saturable and Kerr NLR with the incident photon energy. We numerically evaluate the proportion of these two mechanisms in different wavelengths by a modified NLR equation. The band tail of nc-Si:H appears to play a crucial role in such NLR responses.
The preparation of a new antiwear composites based on polyurethane (PU) elastomer blended and modified with ultra-high molecular weight polyethylene (UHMWPE) has been described. The performance of PU-based composites (PUC) with different proportions of UHMWPE micropowder was demonstrated with mechanical testing, thermal gravimetric analysis, scanning electron microscopy, and friction and wear testing. Compared with the single PU elastomeric material, the composites showed excellent mechanical properties (including tensile strength, break elongation, and flexible modulus), thermal stability, extremely good wear resistance, and low coefficient of friction, especially in water. PUC fabricated in this study is a kind of typical wear-resistant material, which is especially suitable for water-lubricated bearings widely used in metallurgy, mining, hydraulic engineering, and other harsh working conditions. C
We have carried out an investigation of multiple exciton generation (MEG) in Si quantum dots (QDs) and its application in optoelectronic devices. A simple yet effective statistical model has been proposed based on Fermi statistical theory and impact ionization mechanism. It is demonstrated that the MEG efficiency depends on both the radius of Si QDs and the energy of incident photons, with the MEG threshold energy in the range of ∼2.2–3.1 Eg depending on the dot radius. While limited improvement has been observed in power conversion efficiency of single stage solar cells, MEG in Si QDs exhibits prospective for application in ultraviolet detectors due to the high internal quantum efficiency under short incident light.
The light absorption coefficient of hydrogenated nanocrystalline silicon has been engineered to have a Gaussian distribution by means of absorption modification using a femtosecond laser. The absorption-modified sample exhibits a significant absorption enhancement of up to ∼700%, and the strong absorption does not depend on the incident light. We propose a model responsible for this interesting behavior. In addition, we present an optical limiter constructed through this absorption engineering method.
As a byproduct of the coal gasification process, a large amount of coal gasification slag is generated. The failure to fully dispose of it has caused the occupation of land resources and environmental pollution. Before its comprehensive utilization, the carbon and ash constituents must be separated, for which flotation is an effective method. However, the small difference in surface hydrophobicity of them cannot result in a high-efficiency separation. Therefore, a colliding flow pulp conditioning device (CFPCD) was proposed in this work to improve the interaction between the collector droplets and fine particles, and strengthen the modification of collector on the particle surface by generating a properly constructed turbulent flow field. Computational fluid dynamics (CFD) was employed to simulate the internal flow field of CFPCD to obtain the critical flow field parameters, such as the velocity, strain rate, turbulent kinetic energy, turbulent dissipation rate, and turbulent eddy scale. Additionally, particle wrap angle measurements and flotation tests were conducted to verify the performance of pulp conditioning. The results showed that a velocity gradient was obvious in the inner cylinder colliding flow area, thereby inducing the large strain rate and the intense turbulence, which were responsible for the pulp homogenization and the enhanced particle-collector interaction. With the feeding velocity increased, the fluid shear was larger and the improved performance was more obvious. According to the flotation results, the maximum recovery of unburned carbon was obtained with the feeding velocity equal to 2.5 m/s, which was consistent with the tendency of wrap angle. Meanwhile, the loss on ignition of the tailings reached the optimal value, corresponding to 9.94%.
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