Carbon-based electronics is a promising alternative to traditional silicon-based electronics as it could enable faster, smaller and cheaper transistors, interconnects and memory devices. However, the development of carbon-based memory devices has been hampered either by the complex fabrication methods of crystalline carbon allotropes or by poor performance. Here we present an oxygenated amorphous carbon (a-COx) produced by physical vapour deposition that has several properties in common with graphite oxide. Moreover, its simple fabrication method ensures excellent reproducibility and tuning of its properties. Memory devices based on a-COx exhibit outstanding non-volatile resistive memory performance, such as switching times on the order of 10 ns and cycling endurance in excess of 10(4) times. A detailed investigation of the pristine, SET and RESET states indicates a switching mechanism based on the electrochemical redox reaction of carbon. These results suggest that a-COx could play a key role in non-volatile memory technology and carbon-based electronics.
Nanoscale memory devices, whose resistance depends on the history of the electric signals applied, could become critical building blocks in new computing paradigms, such as brain-inspired computing and memcomputing. However, there are key challenges to overcome, such as the high programming power required, noise and resistance drift. Here, to address these, we present the concept of a projected memory device, whose distinguishing feature is that the physical mechanism of resistance storage is decoupled from the information-retrieval process. We designed and fabricated projected memory devices based on the phase-change storage mechanism and convincingly demonstrate the concept through detailed experimentation, supported by extensive modelling and finite-element simulations. The projected memory devices exhibit remarkably low drift and excellent noise performance. We also demonstrate active control and customization of the programming characteristics of the device that reliably realize a multitude of resistance states.
It is shown herein that the electrochemical metal printing system based on hollow atomic force microscope (AFM) cantilevers for the local delivery of precursor species is capable of covering additive manufacturing at different length scales, from submicrometer to submillimeter, within the same printed object by dynamically adjusting printing parameters while keeping the same nozzle diameter. The interplay among the lateral voxel dimensions, nozzle aperture, and pressure is rationalized, while keeping other deposition parameters fixed. An accurate control of the voxel area over two orders of magnitude is achieved by modulation of the applied pressure including on‐the‐fly tailoring of the individual voxel size during printing with the same nozzle. Capabilities of this printing method are highlighted by fabrication of a helix of four copper wires in a layer‐by‐layer manner, whereby each wire is printed with a different diameter. A significant throughput increase is thus obtained by the careful adjustment of voxel dimensions for different features within the same object, allowing a higher fabrication speed for larger structures, while keeping a high enough spatial resolution for their delicate parts.
This paper reports an amorphous carbon (a-C) contact coating for ultra-low-power curved nanoelectromechanical (NEM) switches. a-C addresses important problems in miniaturization and low-power operation of mechanical relays: i) the surface energy is lower than that of metals, ii) active formation of highly localized a-C conducting filaments offers a way to form nanoscale contacts, and iii) high reliability is achieved through the excellent wear properties of a-C, demonstrated in this paper with more than 100 million hot switching cycles. Finally, a full inverter using a-C contacts is fabricated to demonstrate the viability of the concept.
Carbon-based nonvolatile resistive memories are an emerging technology. Switching endurance remains a challenge in carbon memories based on tetrahedral amorphous carbon (ta-C). One way to counter this is by oxygenation to increase the repeatability of reversible switching. Here, we overview the current status of carbon memories. We then present a comparative study of oxygen-free and oxygenated carbon-based memory devices, combining experiments and molecular dynamics (MD) simulations Index Terms-Nonvolatile memory, oxygenated carbon, RRAM, tetrahedral amorphous carbon, diamond-like carbon
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