Photopolymerization of polymer-coated solid substrates with linearly polarized light is shown to induce an anisotropic, uniaxial orientation of polymer molecules. The linearly photopolymerized (LPP) layers exhibit UV dichroism and optical anisotropy. The resulting anisotropic dispersive surface interaction forces are shown to align adjacent liquid crystals parallel. A qualitative microscopic model is presented. The new LPP-alignment technique allows to generate homogeneous LC-director pattern with different azimuthal director angles on the same substrate requiring no mechanical treatment. The use of LPP substrates in liquid crystal displays (LCDs) is shown to enable to combine different electrooptical effects-such as twisted nematic (TN) and parallel configurations-in the same hybrid LCD. Besides from high-contrast LPP-aligned TN-LCDs, LPP-aligned supertwisted nematic (STN)-LCDs exhibiting steep transmission-voltage characteristics are presented.
Using a photoalignment technique with a sulphonic azo-dye as the surfactant aligning material, we fabricated electrically tunable liquid crystal q-plates with topological charge 0.5, 1.5 and 3 for generating optical vortex beams with definite orbital angular momentum (OAM) 1,3 and 6 per photon (in units of ¯h), respectively. We carried out several tests on our q-plates, including OAM tomography, finding excellent performances. These devices can have useful applications in general and quantum optics.
The model of the rotational diffusion of the azo-dye molecules under the action of polarized uv light was used to explain the formation of the photoinduced order in azo-dye layers. We consider both the approximations of negligible and strong molecular interaction during the process of the reorientation under the field of a polarized light. We constructed an experimental setup, based on a photoelastic modulator, that allows accurate in situ measurements of the phase retardation ␦ of thin film as a function of the exposure time t exp and exposure power W ͑W/cm 2 ͒. A good agreement with experiment was observed. Fitting the experimental curves ␦͑t exp ͒ for different power values W, we can estimate the coefficient of rotational diffusion D, azo-dye order parameter S͑t exp ͒, and other parameters of the rotational diffusion model.
Semiconductor nanorods (NR) emit polarized light, which is expected to bring manifold benefits, in terms of brightness and color enhancement, for modern liquid-crystal displays (LCD). In this regard, photoaligned nanorod enhancement films (NREF) for color and polarization conversion for LCD backlights are introduced here. The photoinduced anchoring forces, by the photoalignment layer, stimulate well-ordered self-assembly of NR in the thin polymer films. Green and red emitting NR with a quantum yield of ≈80% are aligned unidirectionally and in-plane, showing a polarization ratio of >7:1 and a degree of polarization of >0.81. The photoalignment technique facilitates the fabrication of mixed and multiple stacked NREF for LCDs, which improves the color gamut and polarization efficiency, and is thus expected to increase the optical efficiency of conventional LCDs by ≈60%.
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