The thermodynamic temperature of the point of inflection of the melting transition of Re-C, Pt-C and Co-C eutectics has been determined to be 2747.84 ± 0.35 K, 2011.43 ± 0.18 K and 1597.39 ± 0.13 K, respectively, and the thermodynamic temperature of the freezing transition of Cu has been determined to be 1357.80 ± 0.08 K, where the ± symbol represents 95% coverage. These results are the best consensus estimates obtained from measurements made using various spectroradiometric primary thermometry techniques by nine different national metrology institutes. The good agreement between the institutes suggests that spectroradiometric thermometry techniques are sufficiently mature (at least in those institutes) to allow the direct realization of thermodynamic temperature above 1234 K (rather than the use of a temperature scale) and that metal-carbon eutectics can be used as high-temperature fixed points for thermodynamic temperature dissemination. The results directly support the developing mise en pratique for the definition of the kelvin to include direct measurement of thermodynamic temperature.

The precision blackbody sources developed at the All-Russian Institute for Optical and Physical Measurements (Moscow, Russia) and their characteristics are analyzed. The precision high-temperature graphite blackbody BB22p, large-area high-temperature pyrolytic graphite blackbody BB3200pg, middle-temperature graphite blackbody BB2000, low-temperature blackbody BB300, and gallium fixed-point blackbody BB29gl and their characteristics are described.

The National Institute of Standards and Technology (NIST) has developed a new facility for the characterization of the infrared spectral emissivity of samples between 150 and 1,000 • C. For accurate measurement of the sample surface temperatures above 150 • C, the system employs a high-temperature reflectometer to obtain the surface temperature of the sample. This technique is especially useful for samples that have significant temperature gradients due to the thermal conductivity of the sample and the heating mechanism used. The sample temperature is obtained through two measurements: (a) an indirect sample emissivity measurement with an integrating sphere reflectometer and (b) a relative radiance measurement (at the same wavelengths as in (a)) of the sample as compared to a blackbody source. The results are combined with a knowledge of the blackbody temperature and Planck's law to obtain the sample temperature. The reflectometer's integrating sphere is a custom design that accommodates the sample and heater to allow reflectance measurements at temperature. The sphere measures the hemispherical-nearnormal (8 • ) reflectance factor of the sample compared relative to a previously calibrated room-temperature reference sample. The reflectometer technique of sample temperature measurement is evaluated with several samples of varying reflectance. Temperature results are compared with values simultaneously obtained from embedded thermocouples and temperature-drop calculations using a knowledge of the sample's thermal conductivity.

The eutectic alloys rhenium-carbon, platinum-carbon and cobalt-carbon have been proposed as reference standards for thermometry, with temperature and uncertainty values specified within the mise en pratique of the definition of the kelvin. These alloys have been investigated in a collaboration of eleven national measurement institutes and laboratories. Published results reported the point-of-inflection in the melting curve with extremely low uncertainties. However, to be considered as standards it is necessary to stipulate what phenomenon a temperature value has been ascribed to; specifically, this should be a thermodynamic state. Therefore, the data have been further evaluated and the equilibrium liquidus temperatures determined based on a consideration of limits and assuming a rectangular probability distribution. The values are: for rhenium-carbon 2747.91 ± 0.44 K, for platinum-carbon 2011.50 ± 0.22 K and for cobalt-carbon 1597.48 ± 0.14 K, with uncertainties at approximately a 95% coverage probability. It is proposed that these values could be used as Metrologia

During an international comparison of radiation temperature measurements performed at the All-Russian Institute for Optophysical Measurements (VNIIOFI), Moscow, in June 1997 by participants from the VNIIOFI, the National Physical Laboratory (NPL), Teddington, and the Physikalisch-Technische Bundesanstalt (PTB), Braunschweig, detailed measurements of the characteristics of two different types of high-temperature black-body source took place. Both of the black bodies consisted of a pyrolytic-graphite cavity and differed only in the design of the electrodes, which were either axial or coaxial. All investigations were carried out covering a temperature range from 1380 K to 3100 K. The electrical characteristics of the black bodies were investigated at all temperature points; and measurements of the temperature drift were performed to determine the stability of the systems in constant-current mode and in optical-feedback control mode. The uniformity of the black-body radiation field was measured in the radiance mode by using narrowband, interference-filter-based radiometers with imaging optics from the NPL and in the irradiance mode by using broadband-filter detectors from the PTB to scan the irradiated area. The results confirm the suitability of the BB3200 for both radiance and irradiance measurements at national metrological institutes.

High-temperature fixed-point blackbodies based on Re-C and TiC-C metal-carbon eutectic alloys are being investigated for use as radiance and irradiance sources for precise measurements in radiometry, photometry and radiation thermometry above the conventionally assigned values of temperatures on the ITS-90 scale. Graphite crucibles having inner diameters varying between 4 mm and 10 mm were used to prepare the metal-carbon and metal carbide-carbon eutectics; the cells were designed and manufactured at VNIIOFI, Russia using high-purity materials.The melting and solidification temperatures of the cells were measured. Their reproducibility was investigated. The radiance reproducibility of the Re-C and TiC-C fixed points was found to be from 0.01% to 0.03% at 650 nm wavelength depending on the cell. Preliminary investigations of ZrC-C fixed-point reproducibility have been carried out. The radiance of all measured cells agreed at the solidification point within 0.02%.

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The realization and the dissemination of spectral radiance and radiance temperature scales in the temperature range of −50 to 250 • C and spectral range of 3-13 µm at the National Institute of Standards and Technology are described. The scale is source-based and is established using a suite of blackbody radiation sources, the emissivity and temperature of which have been thoroughly investigated. The blackbody emissivity was measured using the complementary approaches of modeling, reflectometry, and the intercomparison of the spectral radiance of sources with different cavity geometries and coatings. Temperature measurements are based on platinum resistance thermometers and on the direct use of the phase transitions of pure metals. Secondary sources are calibrated using reference blackbody sources, a spectral comparator, a controlled-background plate, and a motion control system. Included experimental data on the performance of transfer standard blackbodies indicate the need for development of a recommended practice for their specification and evaluation. Introduced services help to establish a nationwide uniformity in metrology of nearambient thermal emission sources, providing traceability in spatially and spectrally resolved radiance temperature, spectral radiance, and background-corrected effective emissivity. S. N. Mekhontsev (B) · L. M. Hanssen Optical Technology Division (844), National