The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New geochemical and chemostratigraphical data and Ar-Ar age determinations for several units of the Breccia Museo deposits (~39 ka), correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber.

Major and trace element analyses plus six new 40Ar/39Ar data obtained on feldspar separates for selected igneous rocks belonging to the Oligo‐Miocene igneous activity of Sardinia are reported here. The rocks show “subduction‐related” geochemical characteristics, ascribed to the metasomatic modification of a mantle wedge developed above a W/NW directed subduction system involving the recycling of Neo‐Tethyan oceanic lithosphere beneath the southern European margin. The 40Ar/39Ar data shift back the beginning of the igneous activity in Sardinia to late Eocene (38.28 ± 0.26 Ma), whereas the end of the igneous activity is possibly shifted forward to late middle Miocene (12.24 ± 0.98 Ma). We therefore propose to rename the Oligo‐Miocene igneous phase as the “late Eocene–middle Miocene” phase. Rare earth element inversion modeling on subduction‐related volcanic rocks of Sardinia requires equilibrium with spinel‐lherzolite facies, therefore implying depths of formation lower than ∼80 km. To reach these depths, a 45° dipping slab needs ∼11 to ∼4 Myr (with 1 to 3 cm/yr subduction velocity, respectively), reducing the beginning of Apennine subduction to the ∼49–42 Ma interval. The different models proposed in literature to explain the origin and the evolution of the central western Mediterranean basins are here reviewed and critically discussed.

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Abstract. The lava domes in the northwestern (Cuma), northern (Punta Marmolite) and central (Accademia) parts of the Phlegrean Fields are the subject of this study. The Cuma and Punta Marmolite trachyphonolitic lava domes are among the oldest Phlegrean products cropping out. The Cuma rocks have an agpaitic groundmass, with early alkali feldspar, Fe-rich clinopyroxene, Fe-edenite and sodalite and late rosenbuschite, fluorite, baddeleyite, pyrochlore, britholite, monazite, aegirine (often Zr-rich) and exceptionally Fe–Mn-rich olivine. The bulk-rock compositions at Cuma have some of the highest concentrations of Zn, Mn, Zr, Nb, Th, U and lanthanides among the Phlegrean Fields rocks, and some of the lowest MgO, P2O5, Sr, Eu and Ba. The Punta Marmolite dome is chemically less evolved, and lacks characteristic agpaitic minerals, but features alkali feldspar, sodalite, nepheline and relatively Na-poor, Fe-rich hedenbergite, with rare Ca-rich plagioclase xenocryst cores. The Accademia dome, belonging to the recent activity, is latitic to trachytic in composition, has highly forsteritic olivine (with chromiferous spinel inclusions), calcic plagioclase and Mg-rich diopside (± phlogopite) xenocrysts in an evolved host rock (with phenocrysts and microlites of alkali feldspar, Fe-rich clinopyroxene, Fe-rich amphibole, magnetite, Fe-rich olivine and accessory baddeleyite, zirconolite and fluorite). There is clear evidence of open-system magma crystallization in the form of interaction between a crystallizing, primitive shoshonitic basalt in a reservoir already filled by rather evolved trachytic magma. The magmatic evolution towards the evolved compositions is dominated by crystallization of more and more Na-rich alkali feldspar in a Cl-, F-rich and relatively H2O-poor environment. Input of mafic magma is evident in many trachytic eruptions of the Phlegrean Fields and even in the products of the Campanian Ignimbrite, but eruptions having mineral assemblages rich in xenocryst phases as well as eruptions virtually free of mafic magma input are also frequently observed throughout the history. This suggests a variable pattern of open- and closed-system crystallization, which may or may not be linked to explosive activity, and that can be caused by intermittent supply of basaltic magma from depth