The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New geochemical and chemostratigraphical data and Ar-Ar age determinations for several units of the Breccia Museo deposits (~39 ka), correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber.

Major and trace element analyses plus six new 40Ar/39Ar data obtained on feldspar separates for selected igneous rocks belonging to the Oligo‐Miocene igneous activity of Sardinia are reported here. The rocks show “subduction‐related” geochemical characteristics, ascribed to the metasomatic modification of a mantle wedge developed above a W/NW directed subduction system involving the recycling of Neo‐Tethyan oceanic lithosphere beneath the southern European margin. The 40Ar/39Ar data shift back the beginning of the igneous activity in Sardinia to late Eocene (38.28 ± 0.26 Ma), whereas the end of the igneous activity is possibly shifted forward to late middle Miocene (12.24 ± 0.98 Ma). We therefore propose to rename the Oligo‐Miocene igneous phase as the “late Eocene–middle Miocene” phase. Rare earth element inversion modeling on subduction‐related volcanic rocks of Sardinia requires equilibrium with spinel‐lherzolite facies, therefore implying depths of formation lower than ∼80 km. To reach these depths, a 45° dipping slab needs ∼11 to ∼4 Myr (with 1 to 3 cm/yr subduction velocity, respectively), reducing the beginning of Apennine subduction to the ∼49–42 Ma interval. The different models proposed in literature to explain the origin and the evolution of the central western Mediterranean basins are here reviewed and critically discussed.

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Abstract. The lava domes in the northwestern (Cuma), northern (Punta Marmolite) and central (Accademia) parts of the Phlegrean Fields are the subject of this study. The Cuma and Punta Marmolite trachyphonolitic lava domes are among the oldest Phlegrean products cropping out. The Cuma rocks have an agpaitic groundmass, with early alkali feldspar, Fe-rich clinopyroxene, Fe-edenite and sodalite and late rosenbuschite, fluorite, baddeleyite, pyrochlore, britholite, monazite, aegirine (often Zr-rich) and exceptionally Fe–Mn-rich olivine. The bulk-rock compositions at Cuma have some of the highest concentrations of Zn, Mn, Zr, Nb, Th, U and lanthanides among the Phlegrean Fields rocks, and some of the lowest MgO, P2O5, Sr, Eu and Ba. The Punta Marmolite dome is chemically less evolved, and lacks characteristic agpaitic minerals, but features alkali feldspar, sodalite, nepheline and relatively Na-poor, Fe-rich hedenbergite, with rare Ca-rich plagioclase xenocryst cores. The Accademia dome, belonging to the recent activity, is latitic to trachytic in composition, has highly forsteritic olivine (with chromiferous spinel inclusions), calcic plagioclase and Mg-rich diopside (± phlogopite) xenocrysts in an evolved host rock (with phenocrysts and microlites of alkali feldspar, Fe-rich clinopyroxene, Fe-rich amphibole, magnetite, Fe-rich olivine and accessory baddeleyite, zirconolite and fluorite). There is clear evidence of open-system magma crystallization in the form of interaction between a crystallizing, primitive shoshonitic basalt in a reservoir already filled by rather evolved trachytic magma. The magmatic evolution towards the evolved compositions is dominated by crystallization of more and more Na-rich alkali feldspar in a Cl-, F-rich and relatively H2O-poor environment. Input of mafic magma is evident in many trachytic eruptions of the Phlegrean Fields and even in the products of the Campanian Ignimbrite, but eruptions having mineral assemblages rich in xenocryst phases as well as eruptions virtually free of mafic magma input are also frequently observed throughout the history. This suggests a variable pattern of open- and closed-system crystallization, which may or may not be linked to explosive activity, and that can be caused by intermittent supply of basaltic magma from depth

The "Colli Albani" composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr ( 87 Sr/ 86 Sr= 0.71057-0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite-to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr ( 87 Sr/ 86 Sr = 0.71006-0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the precaldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre-and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting

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We performed petrophysical analyses on 34 clayey samples of different geological origin within the Campania region of Italy in order to determine possible sources of raw materials used to produce ancient pottery. Possible raw material sources can be grouped into high-CaO clays (HCC) and low-CaO clays (LCC). HCC are mainly represented by more recent (Miocene-Pleistocene) basinal sediments whereas LCC tend to be associated with basinal, alluvial, and pyroclastic deposits. A chemical comparison between clayey raw materials, modern ceramic replicas, and Campanian archaeological ceramics of several typologies (common ware, cooking ware, fine tableware, amphorae, and bricks) from 8th century B.C. to the Middle Ages (a total of 350 ceramic samples) indicates that HCC were extensively used for common wares and that these were either mixed with temper or levigated. In contrast, most of the LCC were used for the production of cookware. We also analyzed the technological potential of the sampled raw materials, taking into consideration their actual and possible uses. We observed that most HCC deposits were well suited for tableware and amphorae, whereas LCC were better for cookware and some fine tableware