[1] We present an estimate for the composition of the depleted mantle (DM), the source for mid-ocean ridge basalts (MORBs). A combination of approaches is required to estimate the major and trace element abundances in DM. Absolute concentrations of few elements can be estimated directly, and the bulk of the estimates is derived using elemental ratios. The isotopic composition of MORB allows calculation of parent-daughter ratios. These estimates form the ''backbone'' of the abundances of the trace elements that make up the Coryell-Masuda diagram (spider diagram). The remaining elements of the Coryell-Masuda diagram are estimated through the composition of MORB. A third group of estimates is derived from the elemental and isotopic composition of peridotites. The major element composition is obtained by subtraction of a low-degree melt from a bulk silicate Earth (BSE) composition. The continental crust (CC) is thought to be complementary to the DM, and ratios that are chondritic in the CC are expected to also be chondritic in the DM. Thus some of the remaining elements are estimated using the composition of CC and chondrites. Volatile element and noble gas concentrations are estimated using constraints from the composition of MORBs and ocean island basalts (OIBs). Mass balance with BSE, CC, and DM indicates that CC and this estimate of the DM are not complementary reservoirs.Components: 13,973 words, 9 figures, 8 tables, 2 datasets.
[1] Recycled ancient oceanic crust with variable amounts of aging, or inclusion of sediments of differing types and origins has often been invoked as a source for present-day ocean island basalts (OIB), but the current evidence remains largely qualitative. Previous quantitative modeling has shown that much has to be learned in order to better understand the implications of crustal recycling on mantle heterogeneity. Here, we present new model calculations incorporating recent constraints on subduction-zone processes and the composition of subducted sediments. Modeled compositions of the recycled oceanic crust vary widely as a function of the recycling age and composition of the oceanic crust. HIMU-type sources can only be created by recycling igneous oceanic crust if it has undergone substantial modification during subduction. Although the required modifications are qualitatively consistent with dehydration processes in subduction zones, the many uncertainties prevent a precise estimate of the isotopic composition of ancient recycled igneous crust. Inclusion of sediments increases the isotopic variability and although the resulting Sr and Nd isotopic signatures can be similar to enriched mantle (EM) signatures, the Pb isotopic composition of EMtype OIB is difficult to reconcile with the presence of sediment in their sources. The large variability of modeled compositions of the subducted crust suggests that if mantle heterogeneity is largely formed by crustal recycling, each OIB is likely to have a unique isotopic composition resulting from specific combinations of composition, age and subduction modification of the subducted crust. Given the variability of the recycled components, a small number of relatively well-defined enriched compositions can only be explained if either the subduction processing of oceanic crust is a far better defined process than observation would seem to indicate, or, the intramantle disaggregation and mixing of compositionally diverse recycled materials is surprisingly efficient.
[1] Postglacial basalts from Theistareykir (younger than 10,000 years), northern Iceland, define the depleted end of the spectrum of chemical and isotopic compositions observed in Icelandic volcanics but extend to some of the most enriched chemical and isotopic compositions found in Icelandic tholeiites. A spectacular feature of these basalts is the impressive correlations observed between radiogenic isotope ratios (Sr, Nd, Hf, and Pb) and almost the entire spectrum of major and trace element concentrations and ratios. The radiogenic isotope and major and trace element compositions are little affected by crystal fractionation and are essentially unaffected by interaction with the preexisting crust. The Theistareykir basalts must therefore be relatively close in composition to primary melts from the mantle. Consequently, their chemical and isotopic compositions provide a unique opportunity to investigate the nature of melting beneath Iceland and the geochemical character and origin of the mantle source. Large variations in incompatible element abundances require source heterogeneity, as well as variable extents of melting, to be important factors in determining the final chemical composition of the melts. Melting integrates over a large pressure range and is dominated by melting a depleted peridotite similar to the ambient depleted North Atlantic mantle. The isotopically enriched component is of relatively minor abundance and probably has a lower solidus temperature compared to the depleted component. More than one isotopically enriched component must be involved, but it is difficult to identify the end-member compositions using those of the lavas because of preeruptive averaging and damping of the enriched isotopic signals by mixing with the ambient depleted mantle or melts thereof, suggesting that the isotopic signals in Icelandic melts represent a somewhat muted isotopic signal of the enriched component(s) in the Icelandic source mantle. Comparison of the isotopic arrays of Icelandic basalts with those of global OIB suggests that the dominant enriched
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