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The prograde, high pressure, transition from antigorite serpentinite to enstatite-olivine rock occurs along a tectonically undisturbed pro®le at Cerro del Almirez, SE Spain. The reactant assemblage is antigorite + olivine with tremolite rimming precursor diopside. The product assemblage of tremolite + chlorite + enstatite + olivine has a spinifex-like texture with arborescent or radiating olivine elongated parallel to [001] and with radially grown enstatite. Product enstatite is very poor in Al 2 O 3 . Due to numerous oriented submicroscopic inclusions of chromian magnetite, product olivine has a brownish pleochroism and a bulk chromium content similar to precursor antigorite. Titanian clinohumite with a ¯uorine content of 0.45±0.50 wt% persisted beyond the breakdown of antigorite. The partitioning of iron and magnesium amongst the silicate phases is almost identical to that at lower pressures. Average K d values Mn/Mg and Ni/Mg are 0.17 and 0.70 for antigorite-olivine pairs and 1.83 and 0.22 for orthopyroxene-olivine pairs, respectively. These data are useful in discriminating generations of olivine grown on each other. From the ®eld data a phase diagram topology for a portion of the system CaO-MgO-SiO 2 -H 2 O is derived. This topology forms the basis for extrapolations into inaccessible P-T regions.

This study provides new constraints on fast cooling and exhumation rates of high‐pressure metamorphic rocks in young active mountain belts. Ion microprobe (SHRIMP) U–Pb analysis of zircon in a pyroxenite layer of the Cerro del Almirez ultramafic rocks (Nevado‐Filábride Complex, southern Spain) gave an age of 15.0 ± 0.6 Myr (95% c.l.). Mineral inclusions demonstrate that zircon formed close to the high‐pressure peak. Combined with previous fission track data, the 15 Myr age suggests high cooling (˜ 80 °C Myr−1) and exhumation (˜1.2 cm yr−1) rates for the unit. The new results indicate that both the Nevado‐Filábride Complex and the overlying Alpujárride Complex, with somewhat higher ages and exhumation rates, underwent similar metamorphic evolutions at different times. This implies that the Alpujárride rocks were exhumed when the Nevado‐Filábride was subducting and that the same tectonic scenario propagated from one portion of the Betic Cordilleras to another.

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International audienceThe Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe3+/FeTotal(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe3+/FeTotal ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe3+-rich antigorite (Fe3+/FeTotal = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe3+/FeTotal(BR) (=0.34–0.41), the crystallization of Fe2+-rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe3+-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe2+-rich phases could promote hematite crystallization and a subsequent increase in fo2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge