The identification of syn-and late-orogenic flysch deposits, extending from the Betic Cordillera to the Southern Apennines, assists in the reconstruction of the tectonic-sedimentary evolution of the perimediterranean chains. A microplate was located between the European and African Plates during the Late Jurassic-Early Cretaceous, bordered northwards by the Piemontese Ocean and southwards by another (North Africa 'Flysch' Basin or Maghrebian) Ocean. The Piemontese Ocean and the northern margin of the microplate were structured from the Late Cretaceous to the Eocene to create an Eo-alpine Chain. The southern margin of the microplate was deformed in the Aquitanian, when the internal areas of the Maghrebian Ocean were characterized by syn-orogenic flysch deposits. This episode culminated with metamorphism (25-22 Ma) and nappe emplacement, which destroyed the former palaeogeography and created an orogenic belt (AlKaPeCa). Afterwards, a lower Burdigalian late-orogenic cycle started in the deformed area, which as a result of the opening of the Algero-Provencal Basin, caused the fragmentation of the AlKaPeCa, its thrusting on the 'Flysch' Basin and the collision with the North Africa and South Iberia Margins. These latter were folded and thrusted, the 'Flysch' Units pushed over the External Domain and also back-thrusted. Langhian late-orogenic deposits suture the new tectonic features. Finally, the whole orogen was thrust onto the foredeep during the Middle-Late Miocene. Terra Nova, 5, 525-544, 1993 (0 5 ;;I 0 r: GI 0 n m z m I z 0 n m z m < v) 2 \ 5 m 0 m 0 GI m z n c n n m ! E 0 2 VI v) VI

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Terra Nova, 24, 34–41, 2012 Abstract The origin of the Numidian Formation (latest Oligocene to middle Miocene), characterized by ultra‐mature quartzose arenites with abundant well‐rounded frosted quartz grains, remains controversial. This formation, sedimented in the external domain of the Maghrebian Flysch Basin, displays three characteristic stratigraphic members with marked longitudinal (proximal–distal) and transverse (along‐chain) variations with palaeogeographical importance. The origin of the Numidian supply is related to the outward tectogenetic propagation when a forebulge evolved in the African foreland, leading to the erosion of African cratonic areas rich in quartzose arenites (Nubian Sandstone‐like). The ages of the Numidian Formation checked by Betic, Maghrebian and Southern Apennine data suggest a timing for the accretionary orogenic wedge, earlier in the Betic‐Rifian Arc (after middle Burdigalian), later in the Algerian‐Tunisian Tell (after late Burdigalian) and afterwards in Sicily and the Southern Apennines (after Langhian). A geodynamic evolutionary model for the central‐western Mediterranean is proposed.

Although diverse microbial metabolisms are known to induce the precipitation of carbonate minerals, the mechanisms involved in the bacterial mediation, in particular nucleation, are still debated. The study of aragonite precipitation by Chromohalobacter marismortui during the early stages (3-7 days) of culture experiments, and its relation to bacterial metabolic pathways, shows that: (1) carbonate nucleation occurs after precipitation of an amorphous Ca phosphate precursor phase on bacterial cell surfaces and/or embedded in bacterial films; (2) precipitation of this precursor phase results from local high concentrations of PO(4)(3-) and Ca(2+) binding around bacterial cell envelopes; and (3) crystalline nanoparticles, a few hundred nanometres in diametre, form after dissolution of precursor phosphate globules, and later aggregate, allowing the accretion of aragonite bioliths.

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Abstract:The Anisian-Carnian Verrucano Group of the Tuscan Metamorphic Units and the Triassic-Hettangian Pseudoverrucano Formation of the homonymous unit are mainly continental redbeds occurring in Tuscany at the base of the Alpine orogenic cycle. A study carded out throughout the Apennine, Maghrebian and Betic Chains emphasized the presence in all these orogenic belts of deposits more or less coeval and similar both to the metamorphic Verrucano and to the unmetamorphosed Pseudoverrucano. Thus, the distinction of Verrucano and Pseudoverrucano successions has a palaeogeographical and geodynamic importance at the scale of the Western Mediterranean. Both successions developed during the continental rift stage of Pangaea, which led to later break-up at the edges of a future microplate, interposed between the Europe, Africa and Adria-Apulia plates, but they are characterized by different tectonometamorphic evolution. Pseudoverrucano-like deposits, devoid of Alpine metamorphism, characterize the highest tectonic units of the nappe stack and they overthrust units bearing Verrucano-like deposits. These latter show an Alpine tectonometamorphic history marked during the Miocene by intense deformation and HP/LT metamorphism (at pressures in the range of 0.8-2 GPa), followed by a retrograde phase associated with decompression, suggesting subduction and subsequent exhumation of continental crust. Intriguing palaeogeographical problems arise from the analysis of Verrucanobearing units, because the same evolution seems to characterize both units considered to belong to a realm similar to that of the north-verging Austroalpine nappe system and some units referred to the south-verging fold-thrust belt derived from the Adria-Apulia palaeomargin.

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Three types of glaucony grains were identified in the late Eocene (~35.5–34.1 Ma) sediments from Ocean Drilling Program (ODP) Hole 696B in the northwestern Weddell Sea (Antarctica). The grains are K2O-rich (~7 wt%) and formed by smectite-poor interstratified ~10 Å glauconite-smectite with flaky/rosette-shaped surface nanostructures. Two glaucony types reflect an evolved (types 1 and 2 glaucony; less mature to mature) stage and long term glauconitization, attesting to the glaucony grains being formed in situ, whereas the third type (type 3 glaucony) shows evidences of alteration and reworking from nearby areas. Conditions for the glaucony authigenesis occurred in an open-shelf environment deeper than 50 m, under sub-oxic conditions near the sediment-water interface. These environmental conditions were triggered by low sedimentation rates and recurrent winnowing action by bottom-currents, leading to stratigraphic condensation. The condensed glaucony-bearing section provides an overview of continuous sea-level rise conditions pre-dating the onset of Antarctic glaciation during the Eocene-Oligocene transition. Sediment burial, drop of O2 levels, and ongoing reducing (postoxic to sulphidic) conditions at Hole 696B, resulting in iron-sulphide precipitation, were a key limiting factor for the glauconitization by sequestration of Fe2+.