• Data on occurrence and levels of glyphosate residues in EU soils is very limited.• Glyphosate and its metabolite AMPA were tested in 317 EU agricultural topsoils.• 21% of the tested EU topsoils contained glyphosate, and 42% contained AMPA.• Both glyphosate and AMPA had a maximum concentration in soil of 2 mg kg Approval for glyphosate-based herbicides in the European Union (EU) is under intense debate due to concern about their effects on the environment and human health. The occurrence of glyphosate residues in European water bodies is rather well documented whereas only few, fragmented and outdated information is available for European soils. We provide the first large-scale assessment of distribution (occurrence and concentrations) of glyphosate and its main metabolite aminomethylphosphonic acid (AMPA) in EU agricultural topsoils, and estimate their potential spreading by wind and water erosion. Glyphosate and/or AMPA were present in 45% of the topsoils collected, originating from eleven countries and six crop systems, with a maximum concentration of 2 mg kg −1. Several glyphosate and AMPA hotspots were identified across the EU. Soil loss rates (obtained from recently derived European maps) were used to estimate the potential export of glyphosate and AMPA by wind and water erosion. The estimated exports, result of a conceptually simple model, clearly indicate that particulate transport can contribute to human and environmental exposure to herbicide residues. Residue threshold values in soils are urgently needed to define potential risks for soil health and off site effects related to export by wind and water erosion.
Abstract--Power systems have traditionally been designed to provide flexibility in a context where demand is met by bulk generation. The integration of variable and uncertain renewable generation sources, such as wind, increases the flexibility needed to maintain the load-generation balance. This paper aims to provide a systematic approach to evaluate the flexibility level and investigate the role of flexibility in generation planning and market operation. An 'offline' index is proposed to estimate the technical ability of both the individual generators and the generation mix to provide the required flexibility. A dedicated unit construction and commitment (UCC) algorithm, able to consider plant investment and operation costs, is developed to determine the optimal investments in flexible generating units. Market simulation models are then implemented to determine the profits obtained from providing flexibility in different market designs. An adapted RTS-96 system is used to test the proposed models and the flexibility metric. Results demonstrate the validity of the UCC algorithm and the coherence of the proposed flexibility index. The analysis of the profits of flexibility shows that the market design plays an important role in the efficient deployment and subsequent profitability of flexibility resources.Index Terms-Flexibility index, wind power, unit commitment and construction, market design, profitability, day-ahead market, balancing market, rolling clearing.
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