Abstract. Modelling stellar atmospheres becomes increasingly demanding as more accurate observations draw a more complex picture of how real stars look like. What could be called a normal star becomes increasingly rare because of, e.g., significant deviations from the classical solar abundance pattern and clear evidence for stratification of elements in the atmospheres as well as surface inhomogeneities (spots) causing further severe deviations from "standard" atmospheres. We describe here a new code for calculating LTE plane-parallel stellar model atmospheres for early and intermediate type of stars which has been written in Compaq Fortran 95 and can be compiled for Windows and Linux/UNIX computer platforms. The code is based on modified 9 subroutines (Kurucz) and on spectrum synthesis codes written by V. Tsymbal with the main modifications of input physics concerning the block for opacity calculation. Each line contributing to opacity is taken into account for modelling the atmosphere, similar to synthetic spectrum calculations. This approach, which we call the line-by-line (LL) technique, avoids problems resulting from statistical methods (ODF, OS) and allows to calculate complex models with abundances which are not simply scaled from a standard pattern (usually the solar abundances) and which can be even depth dependent. Stratification is considered in this context as an empirical input parameter which has to be derived from observations. Due to the implemented numerical methods, mainly in the opacity calculation module, our code produces model atmospheres with modern PCs in a time comparable to that required by classical routines.

Abstract. We present the evidence for abundance stratification in the atmosphere of the rapidly oscillating Ap star γ Equ. Ca, Cr, Fe, Ba, Si, Na seem to be overabundant in deeper atmospheric layers, but normal to underabundant in the upper layers with a transition in the typical line forming region of −1.5 < log τ5000 < −0.5. This stratification profile agrees well with diffusion theory for Ca and Cr, developed for cool magnetic stars with a weak mass loss of ≈2.5 × 10 −15 M yr −1 . Pr and Nd from the rare earth elements have an opposite profile. Their abundance is more than 6 dex higher above log τ5000 ≈ −8.0 than in the deeper atmospheric layers. We further discuss the implications of abundance stratification in the context of radial velocity amplitudes and phases observed by Kochukhov & Ryabchikova (2001) for a variety of spectral lines and elements using high spectral and time resolved, high S/N observations.

Context. For an asteroseismic modeling, the analysis of the high-accuracy light curves delivered by the Kepler satellite mission needs support by ground-based multi-colour and spectroscopic observations. Aims. We determine the fundamental parameters of SPB and β Cep candidate stars observed by the Kepler satellite mission and estimate the expected types of non-radial pulsators. Methods. We compare newly obtained high-resolution spectra with synthetic spectra computed on a grid of stellar parameters assuming LTE and check for NLTE effects for the hottest stars. For comparison, we determine T eff independently from fitting the spectral energy distribution of the stars obtained from the available photometry. Results. We determine T eff , log g, micro-turbulent velocity, v sin i, metallicity, and elemental abundance for 14 of the 16 candidate stars, two of the stars are spectroscopic binaries. No significant influence of NLTE effects on the results could be found. For hot stars, we find systematic deviations of the determined effective temperatures from those given in the Kepler Input Catalogue. The deviations are confirmed by the results obtained from ground-based photometry. Five stars show reduced metallicity, two stars are He-strong, one is He-weak, and one is Si-strong. Two of the stars could be β Cep/SPB hybrid pulsators, four SPB pulsators, and five more stars are located close to the borders of the SPB instability region.

Context. Eclipsing, spectroscopic double-lined binary star systems (SB2) are excellent laboratories for calibrating theories of stellar interior structure and evolution. Their precise and accurate masses and radii measured from binary dynamics offer model-independent constraints and challenge current theories of stellar evolution. Aims. We aim to investigate the mass discrepancy in binary stars. This is the significant difference between stellar components' masses measured from binary dynamics and those inferred from models of stellar evolution via positions of the components in the T eff -log g Kiel diagram. We study the effect of near-core mixing on the mass of the convective core of the stars and interpret the results in the context of the mass discrepancy. Methods. We fit stellar isochrones computed from a grid of mesa stellar evolution models to a homogeneous sample of eleven highmass binary systems. Two scenarios are considered, where individual stellar components of a binary system are treated independent of each other and where they are forced to have the same age and initial chemical composition. We also study the effect of the microturbulent velocity and turbulent pressure on the atmosphere model structure and stellar spectral lines, and its link with the mass discrepancy.Results. We find that the mass discrepancy is present in our sample and that it is anti-correlated with the surface gravity of the star. No correlations are found with other fundamental and atmospheric parameters, including the stellar mass. The mass discrepancy can be partially accounted for by increasing the amount of near-core mixing in stellar evolution models. We also find that ignoring the microturbulent velocity and turbulent pressure in stellar atmosphere models of hot evolved stars results in overestimation of their effective temperature by up to 8%. Together with enhanced near-core mixing, this can almost entirely account for the ∼30% mass discrepancy found for the evolved primary component of V380 Cyg. Conclusions. We find a strong link between the mass discrepancy and the convective core mass. The mass discrepancy can be solved by considering the combined effect of extra near-core boundary mixing and consistent treatment in the spectrum analysis of hot evolved stars. Our binary modelling results in convective core masses between 17 and 35% of the stellar mass, in excellent agreement with results from gravity-mode asteroseismology of single stars. This implies larger helium core masses near the end of the main sequence than anticipated so far.