Sodium-ion batteries are promising futuristic large-scale energy-storage devices because of the abundance and low cost of sodium. However, the development and commercialization of the sodium-ion battery solely depends on the use of high-capacity electrode materials. Among the various metal oxides, SnO 2 has a high theoretical specific capacity for sodium-ion battery. However, the enormous volume expansion and low electrical conductivity of SnO 2 hinder its capability to reach the predicted theoretical value. Although different nanostructured designs of electrode materials like SnO 2 nanocomposites have been studied, the effects of other cell components like electrolyte and binder on the specific capacity and cyclic stability are yet to be understood. In the present study, we have investigated the synergistic effect of electrolyte and binder on the performance enhancement of SnO 2 supported on the intertwined network structure of reduced graphene oxide partially open multiwalled carbon nanotube hybrid as anode in sodium-ion battery. Our result shows that sodium carboxyl methyl cellulose and ethylene carbonate/diethyl carbonate as the electrolyte solvent offers a high specific capacity of 688 mAh g –1 and a satisfactory cyclic stability for 500 cycles. This is about 56% enhancement in specific capacity compared to the use of poly(vinylidene fluoride) binder and propylene carbonate as the electrolyte solvent. The present study provides a better understanding of the synergistic role of electrolyte and binder for the development of metal-oxide-based electrode materials for the advancement of the commercialization of sodium-ion battery.
A hierarchical porous carbon framework derived from betel-nut is synthesized and employed as a bifunctional cathode in a Li-O 2 /air battery. The prepared betel nut derived activated porous carbon (BNAPC) material exhibits an ordered and merged tube-like porous morphology and a high specific surface area of 768 m 2 /g. The presence of both meso and micro porous leads to a well-developed 3D interconnected carbon framework, which provides an efficient path for the diffusion of the reactant (oxygen as well as air) and also allows stocking the discharge product of Li 2 O 2 . Therefore, it exhibits a high specific capacity and excellent rate performance. A maximum discharge capacity of 9560 and 2000 mAh/g at a current density of 100 mA/g for oxygen and ambient air respectively as the reactant is achieved. The prepared material also exhibits reversible cyclic stability of 27 cycles with a specific capacity of 1000 mAh/g at a 100 mA/g current density in oxygen atmosphere.
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