This paper examines ferronematic switching in a homeotropic cell in the presence of a magnetic field normal to the cell plane. At low fields we find thresholdless switching of the nematic director, consistent with experimental data. At higher fields, there are three regimes, depending on the strength of the director-ferroparticle coupling. For low coupling, there is an inverse Frederiks effect: the nematic reorientation increases and then reduces, disappearing at a critical field. At intermediate coupling, the reorientation reduces at high fields but remains finite. For high coupling, however, the director switching saturates. There is a dimensionless temperature scale t involving the temperature, the mean nematic elastic constant, the colloidal density and the cell dimension. For low t, high magnetic fields can cause the ferroparticles to segregate. The segregation is coupled to the director distortion, and this can drive the inverse Frederiks transition first order, causing bistability for intermediate fields. These features are perturbed but not changed structurally by the effect of a small bias magnetic field (< 10 Oe) normal to the unperturbed director.
Abstract. Using continuum and statistical mechanical theories, we study the switching properties of a ferronematic in a nematic liquid crystal cell subject to homeotropic boundary conditions at the cell and particle walls. An external magnetic field normal to the cell plane is also imposed. At low fields we find thresholdless switching of the nematic director, consistent with experimental data. At higher fields, there are three regimes, depending on the strength of the anchoring interaction between the director and the ferroparticle orientation. For low anchoring strengths, there is an inverse Frederiks effect, and the nematic reorientation reduces and then disappears continuously at a critical magnetic field. At intermediate fields, the degree of reorientation reduces at high fields but remains finite. For high fields, however, the director switching saturates. The dimensionless temperature scale in the problem involves the temperature, the mean nematic elastic constant, the colloidal density, and the cell dimension. If this quantity is sufficiently low, then high magnetic fields can cause magnetic segregation. The segregation order parameter is coupled to the director distortion, and this can change the inverse Frederiks transition into a first order transition, leading to bistability in an intermediate field regime. These features are perturbed but not changed structurally by the effect of a small bias magnetic field (< 10 Oe) normal to the unperturbed director. Subject to suitable choice of parameters, the theory is also quantitatively consistent with the results of the classic experiment of Chen and Amer in 1983.
The article reports about electric field-induced alignment of the carbon nanoparticles embedded in epoxy matrix. Optical microscopy was performed to consider the effect of the electric field magnitude and configuration, filler morphology, and aspect ratio on alignment process. Characteristic time of aligned network formation was compared with modeling predictions. Carbon nanotube and graphite nanoplatelet rotation time was estimated using an analytical model based on effective medium approach. Different depolarization factor was applied according to the geometries of the particle and electric field.Solid nanocomposites were fabricated by using AC electric field. We have investigated concentration dependence of electrical conductivity of graphite nanoplatelets/epoxy composites using two-probe technique. It was established that the electrical properties of composites with random and aligned filler distribution are differ by conductivity value at certain filler content and distinguish by a form of concentration dependence of conductivity for fillers with different morphology. These differences were explained in terms of the dynamic percolation and formation of various conductive networks: chained in case of graphite nanoplatelets and crossed framework in case of carbon nanotubes filler.
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