Abstract. We report the abundance determination in the atmosphere of the bright halo star HD 221170. The spectra were taken with the Terskol Observatory's 2.0-m telescope with a resolution R = 45 000 and signal-to-noise ratio up to 250 in the wavelength region 3638-10 275 Å. The adopted atmospheric parameters correspond to an effective temperature T eff = 4475 K, a surface gravity log g = 1.0, a microturbulent velocity v micro = 1.7 km s −1 , and a macroturbulent velocity v macro = 4 km s −1 . The abundances of 43 chemical elements were determined with the method of spectrum synthesis. The large overabundances (by 1 dex relative to iron) of elements with Z > 38 are shown to follow the same pattern as the solar r-abundances. The present HD 221170 analysis confirms the non-universality of the r-process, or more exactly the observation that the astrophysical sites hosting the r-process do not always lead to a unique relative abundance distribution for the bulk Ba to Hg elements, the Pb-peak elements, and the actinides.

Abstract. We carried out a detailed analysis of spectra of the unique roAp star HD 101065 (Przybylski's star) near the resonance doublet Li I 6708 Å, using a most complete line list including all possible transitions between REE levels of the NIST database. Our model calculations were performed under two assumptions: a blend of Li and REE lines, and a blend of REE lines only. They prove that Li lines are present in the range 6707.72−6708.02 Å and that the resulting Li abundance is 3.1 dex (in the scale log N(H) = 12.0), while the isotopic ratio 6 Li/ 7 Li is near to 0.3.

Abstract. We present chemical abundances of the mild barium star HD 202109 (ζ Cyg) determined from the analysis of a spectrum obtained by using the 2-m telescope at the Peak Terskol Observatory and a high-resolution spectrometer with R = 80 000, signal to noise ratio >100. We also present the atmospheric parameters of the star determined using various methods including iron-line abundance analysis. For line identifications, we use whole-range synthetic spectra computed from Kurucz's database and the latest lists of spectral lines. Among the determined abundances of 51 elements, those of P, S, K, Cu, Zn, Ge, Rb, Sr, Nb, Mo, Ru, Rh, Pd, In, Sm, Gd, Tb, Dy, Er, Tm, Hf, Os, Ir, Pt, Tl, and Pb were not investigated previously. Assuming that the overabundance pattern of Ba stars is due to binary accretion, the observed abundance pattern of the neutron-capture process elements in HD 202109 can be explained by combining the AGB star nucleosynthesis and the wind accretion scenario.

We investigated the chemical composition of ρ Pup using high-resolution spectral observations taken from the Very Large Telescope and the IUE archives and also spectra obtained at the 1.8 m telescope of the Bohyunsan observatory in Korea. The abundances of 56 chemical elements and the upper limits of Li and Be abundances were determined. The abundance pattern of ρ Pup was found to be similar to that of Am-type stars. The possibility of the influence of the accretion of interstellar gas and dust on the abundance patterns of B-F-type stars is discussed. The plots of the relative abundances of chemical elements in the atmospheres of ρ Pup and δ Sct versus the second ionization potentials of these elements show the correlations. The discontinuities at 13.6 and 24.6 eV-the ionization potentials of hydrogen and helium, respectively, are also exhibited in these plots. These discontinuities can be explained by interaction of the atoms of interstellar gas, mainly hydrogen and helium atoms, with the atoms of stellar photospheres (so-called charge-exchange reactions). Note that only the jumps near 13.6 and 24.6 eV were pointed out in previous investigations of relative abundances versus the second ionization potentials for Am-type stars. The dependencies of the relative abundances of chemical elements on the second ionization potentials of these elements were investigated using the published abundance patterns of B-F-type stars. The correlations of relative and absolute abundances of chemical elements, second ionization potentials, and projected rotational velocities are clearly detected for stars with effective temperatures between 7,000 and 12,000 K. If the correlation of relative abundances and second ionization potentials can be explained by the accretion of interstellar gas on the stellar surfaces, the investigation of these correlations can provide valuable information on the density and velocities of interstellar gas in different regions of the Galaxy and also on the influence of this phenomenon on stellar evolution. The dependencies of the relative abundances of chemical elements on the condensation temperatures of these elements were also found in the atmospheres of ρ Pup, δ Sct, and other B-F-type stars. Ten possible λ Boo-type stars were detected. The effective temperatures of these objects are between 10,900 and 14,000 K.

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