Abstract. We carried out a detailed analysis of spectra of the unique roAp star HD 101065 (Przybylski's star) near the resonance doublet Li I 6708 Å, using a most complete line list including all possible transitions between REE levels of the NIST database. Our model calculations were performed under two assumptions: a blend of Li and REE lines, and a blend of REE lines only. They prove that Li lines are present in the range 6707.72−6708.02 Å and that the resulting Li abundance is 3.1 dex (in the scale log N(H) = 12.0), while the isotopic ratio 6 Li/ 7 Li is near to 0.3.

Context. In atmospheres of magnetic main-sequence stars, the diffusion of chemical elements leads to a number of observed anomalies, such as abundance spots across the stellar surface. Aims. The aim of this study was to derive a detailed picture of the surface abundance distribution of the magnetic chemically peculiar star HD 3980. Methods. Based on high-resolution, phase-resolved spectroscopic observations of the magnetic A-type star HD 3980, the inhomogeneous surface distribution of 13 chemical elements (Li, O, Si, Ca, Cr, Mn, Fe, La, Ce, Pr, Nd, Eu, and Gd) has been reconstructed. The INVERS12 code was used to invert the rotational variability in line profiles to elemental surface distributions. Results. Assuming a centered, dominantly dipolar magnetic field configuration, we find that Li, O, Mg, Pr, and Nd are mainly concentrated in the area of the magnetic poles and depleted in the regions around the magnetic equator. The high abundance spots of Si, La, Ce, Eu, and Gd are located between the magnetic poles and the magnetic equator. Except for La, which is clearly depleted in the area of the magnetic poles, no obvious correlation with the magnetic field has been found for these elements otherwise. Ca, Cr, and Fe appear enhanced along the rotational equator and the area around the magnetic poles. The intersection between the magnetic and the rotational equator constitutes an exception, especially for Ca and Cr, which are depleted in that region. Conclusions. No obvious correlation between the theoretically predicted abundance patterns and those determined in this study could be found. This can be attributed to a lack of up-to-date theoretical models, especially for rare earth elements.

Abstract. As a further step in our Lithium project we present results of abundance determination of some elements in the roAp star HD 60435. Possible NLTE effects were considered. Equivalent widths of spectral lines vary with rotational phase which suggests nonuniform distribution of chemical elements over the stars' surface. Large abundance differences derived from various ions of some rare earth elements indicate their possible vertical stratification. Two spots of enhanced lithium abundance were distinguished at the magnetic poles on HD 60435 and their parameters derived. The rotational axis inclination i = 133• or 47• and surface magnetic field Hs = 3± 1 kG were determined for the first time for HD 60435. The results are compared with HD 83368, the other star with lines of lithium remarkably variable in intensity and wavelength.

Lithium in cool magnetic CP stars in still poorly studied and estimations of the Li abundance in these stars are scarce. There is some evidence of variability of the LiI 6708 Â line, but this variability has not been studied systematicaly. Even the identification of the 6708 Â line with the LiI resonance doublet is still in doubt. This problem is important in the broader context of the Li abundance in various types of stars, as well as for deeper undersfanding of the magnetic star phonomenon itself. The reason for fhis is that the Li abundance in very sensitive to evolutionary status of the stars and their properties, such as the character and intensity of mixing processes.

Abstract. An internacional project "Lithium in magnetic Ap stars" has been run since 1996 with the purpose of creating an observational database allowing systematic studies of the abnormal occurence of lithium on the surface of cool Ap stars. The 2.6 m telescope at the Crimean Astrophysical Observatory, the ESO CAT, ESO 1.52 m telescope with FEROS, the Nordic Optical Telescope, and the 74" telescope at Mount Stromlo were employed to collect observations at the regions of the lithium resonance lines λ 6103 and λ 6708Å.Observations of the roAp-stars HD 83368, HD 60435 and HD 3980 revealed considerable periodical Doppler shifts of the line of lithium λ 6708Å which can be explained by the presence of lithium spots on their surfaces. Conjunction with structures of the magnetic field is apparent.A detailed study of the blend at λ 6708Å in HD 101065 confirmed the anomalous overabundance of lithium amounting to 3.1 dex, as well as unusual isotopic ratio 6 Li/ 7 Li∼ 0.3.

The problem of lithium in chemically peculiar Ap-CP stars has been the subject of debate for many years. The main reason for this is a lack of spectral observations of Ap stars in the neighborhood of the lithium resonance doublet Li I 6708 Å. An international cooperation project on "Lithium in cool CP stars with magnetic fields" was started in 1996. Systematic observations of CP stars in spectral regions of the 6708 Å and 6103 Å lines at the ZTSh (CrAO), CAT (ESO), Feros (ESO), and the 74" telescope of the Mount Stromlo Observatory (Australia) have been used to analyze spectra of several CP stars studied by the way the 6708 Å lithium line varies with the stars' rotational phase. Monitoring of the spectra of the oscillating CP stars (group I) HD 83368, HD 60435, and HD 3980, for which significant Doppler shifts of the Li I 6708 Å line are observed led to the discovery of "lithium spots" on the surface of these stars whose positions are related to the magnetic field structure. Models of the surfaces of these stars with the special program "ROTATE" based on the profiles of the Li I 6708 Å line are used to estimate the size of the spots, their positions on the stars' surface, and the lithium abundances in these spots. A detailed analysis and modelling of the spectra of slowly rotating oscillating CP stars with strong, invariant lithium 6708 Å emission, including blending with lines of the rare earth elements, reveals an enhanced lithium abundance, with the abundance determined from the lithium 6103 Å line being higher than that determined from the 6708 Å line for all the stars. This may indicate vertical stratification of lithium in the atmospheres of CP stars with an anomalous isotopic composition ( 6 Li/ 7 Li = 0.2 -0.5). HD 101065, an ultraslow rotator ( 5 1 sin . i ≈ L ) visible from the poles and with powerful oscillations which cause pulsating line broadening in its spectrum, is unique among these stars. The amount of lithium in the atmosphere of HD 101065 logN(Li) = 3.1 on a scale of logN(H) = 12.0 and the isotope ratio 0.3 Li Li/ 7 6 ≈. The high estimates of 6 Li/ 7 Li may be explained by the production of lithium in spallation reactions and the preservation of surface 6 Li and 7 Li by strong magnetic fields in the upper layers of the atmosphere near the magnetic poles.

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