Purpose. To develop a laser method for initiating a converging cylindrical front of a detonation wave and a method for calculating the kinematic parameters of the cylindrical shell walls, accelerated by the pressure of the detonation products of an external explosive charge. Methodology. An experimental technology for the manufacture of a photosensitive explosive composite and an experimental technique for igniting the surface of its layer with an extended laser beam without the use of a fiber-optic cable are used. The results of simulation modeling the Monte Carlo method were used to study the effect of illumination on the process of ignition of explosives by laser pulsed radiation. For the selected type of photosensitive explosive composite, its explosive and optical characteristics, the distance from the surface of the explosive charge to the lens scattering the laser beam, and taking into account the total area of the expanded beam, the regularities of the distribution of the radiation energy density over the vertical and horizontal sections of the laser beam were studied. Findings. The analysis of the scientific and technical level of methods of shock-wave processing of materials in the region of ultrahigh pressures from the point of view of the fundamental value of the cumulation of energy in the waves of a converging cylindrical detonation and shock front is carried out. Physicomathematical modeling was carried out and the regularities of pressure increase in the wave front were established in the process of approaching the shell walls to the axis. The scientific results of modeling converging cylindrical shells under the influence of the pressure of the explosion products have been analyzed. A method for laser initiation of a converging cylindrical front of a detonation wave has been developed, and a method for calculating the kinematic parameters of the converging walls of a cylindrical shell has been proposed. Originality. A technique has been developed for determining the energy characteristics of an expanded laser beam, calculating the laser radiation energy required to initiate detonation simultaneously on the entire lateral cylindrical surface of a photosensitive explosive composite. The idea of technical implementation of the cumulation of converging cylindrical detonation and shock waves was developed further. A technique has been developed for the numerical determination of the change in the internal average compression rate of the shell during the movement of its walls towards the axis for various ratios of its external radius to the wall thickness and taking into account the increase in pressure in the converging detonation front. Practical value. For the first time, a method for laser initiation of a converging cylindrical front of a detonation wave was developed and a device was tested that forms a converging cylindrical front of a detonation wave and a corresponding shock front in the material under study by the impact of a metal shell converging to the axis. The core of the device is a laser explosive initiation system that uses light-sensitive explosive composites to initiate an explosive charge.
This study aims to analyse physical and chemical changes in hard coal samples under the influence of low-intensity electric fields in comparison to the fragments of ejected coal, as well as the coal samples selected from the zones of high and low outburst hazard. We used physical methods including X-raying, electron paramagnetic resonance, thermogravimetric analysis, differential scanning calorimetry, laser diffraction analysis of particle sizes, IR-spectrometry, nuclear magnetic resonance, and Raman spectroscopy. It has been shown that destruction of coal organic matter (COM) can be caused not only by mechanical impacts or thermal influences but also weak electric fields. Scientific novelty consists in the fact that for the first time we established the identity of the COM destruction mechanism of mechanical-chemical activation and weak electric fields influencing on the previously destabilized coal microstructure. The destruction mechanism is based on thermal field regularities in both cases. The results obtained are of practical significance for the technologies of coal conversion to other products. The research results can be useful in the development of methods for reducing outburst hazard in coal mines.
Purpose. To establish the regularities of the influence of magnetic fields on the peculiarities of changing the chemical and structural characteristics of the coal substance according to the size of microparticles enriched with vitrinite. To formulate a new system of views on the mechanisms of structural and functional transformations of coal substance under the influence of weak external fields. Methodology. The authors used an electric furnace heating up to 320 K that creates a pulsation magnetic field with a strength of up to 4,000 A/m to process dispersed samples of hard coal with a weak magnetic field. The methods of infrared spectroscopy and electron paramagnetic resonance were used in the research. Findings. Experimental works were carried out to estimate the impact of weak fields on the state and properties of coal substance. It is shown that weak energy fields, and the electromagnetic one in particular, are able to reduce the energy barriers of reactions in coal substance due to spin-spin interaction, which leads to the activation of processes at the atomic-molecular level and interfacial interaction. Originality.It is experimentallyestablished that for coal micro-particles with sizes from 0.16 to 0.1 m, enriched with vitrinite, the coupling coefficient decreases after exposure to an external magnetic field, and for micro-particles with sizes less than 0.63 m, this indicator increases. Such changes are caused by the redistribution of hydrogen between aromatic and aliphatic components during free-radical reactions. Changes in the spectrum on vitrinite (0.160.10 mm), are more significant than on inertinite (0.063<0.05 mm). At the same time, the external action of the electromagnetic field has caused the opposite consequences. It is shownthat magnetically stimulated chemical reactions occurring in the coal substance are aimed at the recombination of free radicals with active surface states of the organic mass of coal into stable gas molecules. The results of laboratory studies using the methods of electron magnetic resonance and infrared spectroscopy and infrared spectroscopy allow assuming that the changes in structural characteristics recorded during experiments with low-energy impacts can be considered as intermediatorsfor the matter transformation or changes in the state of coal in preparation for structural and functional transformations.For example, to the sorption interaction or destructive processes with methane generation. Practical values.The magnetic field effect can be used to develop new research methods for the study on elementary processes by electron spin resonance; control spin-dependent phase transitions. The use of magnetic resonance methods allows the usage of magnetically field effects in the form of basic tools for the research on structural defects. The results obtained will be a scientific ground for the development of methods for estimating the parameters of electromagnetic processes in coal to develop new technologies for the extraction and processing of hydrocarbon energy carriers.
Purpose. To study changes in the microstructure of metals after exposure to high-energy plasma jets formed by the cumulation of gas-dynamic flows in a conical target. To estimate the expected state of matter in a strong shock wave compression, taking into account the change in volumetric energy density at the moment of transformation of a solid body plasma into nuclear matter. Methodology. The technique of laser initiation of a profiled front of detonation waves in explosive charges and the corresponding profile of shock waves in materials, methods and techniques for measuring the dynamic parameters of shock-compressed substances are used. Findings. An experimental study on the physicochemical state of a substance that has been processed with extremely high pressures and temperatures during compression by converging shock waves in conical targets has been carried out. Scientific results of physical and mathematical modelling of converging shock waves are analysed. Originality. For the first time, the formation of symmetric plasma jets during gas compression in conical targets has been experimentally observed. For the first time, metallo-physical studies on the microstructure of cast iron and steel have been carried out. These studies were made after the action of high-energy dense plasma jets with a temperature of (2.52.8) × 106K and a pressure 1.12 × 1012 arising from the collision of the jet with a barrier. Iron-55 and copper-64 isotopes were found in the cast iron microstructure near the surface formed by the action of the plasma jet. The main components of the plasma jet were gaseous oxygen, nitrogen, argon, and atomic iron, copper and gold. The fact of formation of isotopes is the result of nuclear reactions. One of the main conditions for the implementation of such reactions is a dense high-temperature plasma. It is assumed that under the action of a strong shock wave in a conical target, in addition to the synthesis reaction, other nuclear reactions with heavy elements can be realized. The ideas about the expected state of matter in a compression shock wave are presented, taking into account the change in the volumetric energy density at the moment of transformation of a solid body plasma into nuclear matter. Practical value. The proposed technique for conducting experimental studies on a shock-compressed substance under the action of extreme temperatures and pressures in conical targets using laser initiation of chemical explosives is of practical importance. The idea of the expected state of matter in the shock wave is also important.
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