Purpose. To establish the regularities of the influence of magnetic fields on the peculiarities of changing the chemical and structural characteristics of the coal substance according to the size of microparticles enriched with vitrinite. To formulate a new system of views on the mechanisms of structural and functional transformations of coal substance under the influence of weak external fields. Methodology. The authors used an electric furnace heating up to 320 K that creates a pulsation magnetic field with a strength of up to 4,000 A/m to process dispersed samples of hard coal with a weak magnetic field. The methods of infrared spectroscopy and electron paramagnetic resonance were used in the research. Findings. Experimental works were carried out to estimate the impact of weak fields on the state and properties of coal substance. It is shown that weak energy fields, and the electromagnetic one in particular, are able to reduce the energy barriers of reactions in coal substance due to spin-spin interaction, which leads to the activation of processes at the atomic-molecular level and interfacial interaction. Originality.It is experimentallyestablished that for coal micro-particles with sizes from 0.16 to 0.1 m, enriched with vitrinite, the coupling coefficient decreases after exposure to an external magnetic field, and for micro-particles with sizes less than 0.63 m, this indicator increases. Such changes are caused by the redistribution of hydrogen between aromatic and aliphatic components during free-radical reactions. Changes in the spectrum on vitrinite (0.160.10 mm), are more significant than on inertinite (0.063<0.05 mm). At the same time, the external action of the electromagnetic field has caused the opposite consequences. It is shownthat magnetically stimulated chemical reactions occurring in the coal substance are aimed at the recombination of free radicals with active surface states of the organic mass of coal into stable gas molecules. The results of laboratory studies using the methods of electron magnetic resonance and infrared spectroscopy and infrared spectroscopy allow assuming that the changes in structural characteristics recorded during experiments with low-energy impacts can be considered as intermediatorsfor the matter transformation or changes in the state of coal in preparation for structural and functional transformations.For example, to the sorption interaction or destructive processes with methane generation. Practical values.The magnetic field effect can be used to develop new research methods for the study on elementary processes by electron spin resonance; control spin-dependent phase transitions. The use of magnetic resonance methods allows the usage of magnetically field effects in the form of basic tools for the research on structural defects. The results obtained will be a scientific ground for the development of methods for estimating the parameters of electromagnetic processes in coal to develop new technologies for the extraction and processing of hydrocarbon energy carriers.
The practical experience of long-term operation of hydrocarbon deposits con- firms the presence of geomechanical processes and their significant impact on the state of the gas-saturated massif of rocks. In fields that are being operated for a long time, the prospects for industrial hydrocarbon accumulation can be associated with secondary gas traps of non-traditional type, in particular, technogenic ones, which are formed in low-pore collectors. The authors carried out a detailed analysis of the well-known gas and gas condensate fields of Ukraine. The Rudkivske gas field of the Western oil-and-gas bearing region was chosen. The purpose of the study is to clarify the geological conditions for the formation of technogenic collectors and attracting additional volumes of gas under the action of a geomechanical factor while operating the Rudkivske gas field. The quoted results of the research prove the effect of gas extraction from the deposits of the J-h horizon on the formation of secondary technogenic collectors by attracting additional volumes of gas from the of ND-4, ND-5, ND-7 productive horizons and the formation of a new (ND-10) one, which subsequently connected to the gas production. Attracting additional gas volumes is due to the gas influx from newly made technogenic collectors, which were formed under the action of a geomechanical factor in the process of long-term development of the field. The formation of technogenic collectors occurred due to the compression of the main reservoir of the Jurassic age (J-h), the deformation of the rock strata, and the decomposition of the overlying rocks, the development of the crack propagation, permeability increase and gas recovery rising. The geomechanical factor management opens the prospect of obtaining additional industrial gas influx in the late stages of the development of gas and gas-condensate fields, by predicting the geological conditions for the formation of improved secondary filtration and capacitive properties favorable to form technogenic gas deposits.
Purpose. Improving the method for determining the ultimate sorption capacity of coal matter using EPR-spectroscopy (electron paramagnetic resonance) by adjusting the proportionality coefficient between the ultimate sorption capacity of coal and the concentration of paramagnetic centers and the conjugation coefficient in accordance with the degree of coalification. Methodology. The ultimate sorption capacity of the matter was estimated by EPR-spectroscopy, based on the content of paramagnetic centers (PMC) in coal, which are able to come into physical (sorption) interaction with molecules of paramagnetic gas (O2) when the pressure increases. Processing of the research results was carried out by methods of mathematical statistics. Findings. Analysis of long-term results for determining the ultimate sorption capacity of coal matter by EPR-spectroscopy was carried out. The analysis testified about the need to adjust the proportionality coefficient between the ultimate sorption capacity of coal and the concentration of paramagnetic centers Na and the conjugation coefficient Ksc, depending on the coal rank metamorphism. The values of the proportionality coefficient by hard coal ranks for the yield of volatile components Vdaf and the reflectivity of vitrinite R° were calculated. Appropriate changes were made to the express-method for estimating the ultimate sorption capacity of coal by the EPR method. Originality. It is proved that the proportionality coefficient β between the ultimate sorption capacity of coal and the concentration of paramagnetic centers Na and the conjugation coefficient Ksc is not a constant value, but changes (decreases) with the degree of metamorphism. It is established that this relationship is satisfactorily characterized by the sigmoid model, whose inflection (on the graph) is confined to the gas and fat ranks of coals (volatile-matter yield is 29 %) and is caused by the second main jump of coalification during a cardinal change in the molecular structure of coal, associated with the completion of the intensive decomposition of the polymer-lipoidin component in the coal matter. Practical values. The express-method was improved for estimating the ultimate sorption capacity of coal by the EPR-method, which differs by specified proportionality coefficients according to ranks in the series of coalification.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.