We obtain the wave velocities of ice‐ and gas hydrate‐bearing sediments as a function of concentration and temperature. Unlike previous theories based on simple slowness and/or moduli averaging or two‐phase models, we use a Biot‐type three‐phase theory that considers the existence of two solids (grain and ice or clathrate) and a liquid (water), and a porous matrix containing gas and water. For consolidated Berea sandstone, the theory underestimates the value of the compressional velocity below 0°C. Including grain‐ice interactions and grain cementation yields a good fit to the experimental data. Strictly speaking, water proportion and temperature are closely related. Fitting the wave velocity at a given temperature allows the prediction of the velocity throughout the range of temperatures, provided that the average pore radius and its standard deviation are known. The reflection coefficients are computed with a viscoelastic single‐phase constitutive model. The analysis is carried out for the top and bottom of a free‐gas zone beneath a gas hydrate‐bearing sediment and overlying a sediment fully saturated with water. Assuming that the bottom‐simulating reflector is caused solely by an interface separating cemented gas hydrate‐ and free gas‐bearing sediments, we conclude that (1) for a given gas saturation, it is difficult to evaluate the amount of gas hydrate at low concentrations. However, low and high concentrations of hydrate can be distinguished, since they give positive and negative anomalies, respectively. (2) Saturation of free gas can be determined from the reflection amplitude, but not from the type of anomaly. (3) The P to S reflection coefficient is a good indicator of high amounts of free gas and gas hydrate. On the other hand, the amplitude‐variation‐with‐offset curves are always positive for uncemented sediments.

Sicily is a thick orogenic wedge formed by (1) the foreland (African) and its Sicilian orogen and (2) the thick-skinned, Calabrian–Peloritani wedge. The crust under central Sicily, from the Tyrrhenian margin to\ud the coastline of the Sicily Channel, has been investigated by the multidisciplinary (SI.RI.PRO.) research project.\ud The project dealt with the nature and thickness of the crust and depth and geometry of the Moho, which is essential in formulating subduction models and improving the knowledge of African and Tyrrhenian–\ud European lithospheres. The results resolve features such as (1) the main orogenic wedge, (2) the very steep, NW–SE-trending regional monocline suggesting inflection of the foreland crust, (3) the deep Caltanissetta synform imaged, for the first time, to about 25 km, and (4) the top of the crystalline basement and the inferred\ud crust–mantle boundary. The SI.RI.PRO. transect confirmed that the NNW-dipping, autochthonous Iblean platform of SE Sicily and its basement extends all the way into central Sicily. Further NW, towards the NNW\ud end of the transect, a large uplift involves the Iblean platform and its underlying basement. The associated gravity anomaly is interpreted as the southern wedge edge of the Tyrrhenian mantle that splits the subducting Iblean–Pelagian (African) continental slab from an overlying synformal stack of allochthonous thrust sheets

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Marine transform faults and associated fracture zones (MTFFZs) cover vast stretches of the ocean floor, where they play a key role in plate tectonics, accommodating the lateral movement of tectonic plates and allowing connections between ridges and trenches. Together with the continental counterparts of MTFFZs, these structures also pose a risk to human societies as they can generate high magnitude earthquakes and trigger tsunamis. Historical examples are the Sumatra-Wharton Basin Earthquake in 2012 (M8.6) and the Atlantic Gloria Fault Earthquake in 1941 (M8.4). Earthquakes at MTFFZs furthermore open and sustain pathways for fluid flow triggering reactions with the host rocks that may permanently change the rheological properties of the oceanic lithosphere. In fact, they may act as conduits mediating vertical fluid flow and leading to elemental exchanges between Earth's mantle and overlying sediments. Chemicals transported upward in MTFFZs include energy substrates, such as H 2 and volatile hydrocarbons, which then sustain chemosynthetic, microbial ecosystems at and below the seafloor. Moreover, up-or downwelling of fluids within the complex system

a b s t r a c t a r t i c l e i n f oA crustal reflection seismic profile, more than 100 km long, was recorded across central Sicily, from the Tyrrhenian shore to the Sicily Channel, to understand the deep structures and the collision mechanisms between Europe and Africa and the subsequent geodynamic evolution. The profile was acquired using explosive sources and 240 active channels recorded by a Sercel 408-XL, 24 bits A/D converter, with a 12 km spread and a 24-fold coverage. The data were processed following a non-conventional procedure in order to preserve the relative amplitudes of the reflections and to better investigate the Sicily deep structures down to the Moho. The main highlighted structures are the dramatic flexure of the Iblean crust, the huge, deeper than expected, trough of Caltanissetta consisting of deep seated thrusts and nappes, and the imbricate thrust system of rigid bodies characterizing the northern Maghrebian chain. We designed an ad hoc acquisition and processing in order to highlight these main geological features in the seismic stacked section. Moreover, the deepest parts of the Caltanissetta trough are imaged for the first time, and its bottom is now fixed at more than 7 s TWT. The giant crustal wedge flexuring the Iblean foreland and the Moho geometries are examinated.

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A gas hydrate reservoir, identified by the presence of the bottom simulating reflector, is located offshore of the Antarctic Peninsula. The analysis of geophysical dataset acquired during three geophysical cruises allowed us to characterize this reservoir. 2D velocity fields were obtained by using the output of the pre-stack depth migration iteratively. Gas hydrate amount was estimated by seismic velocity, using the modified Biot-Geerstma-Smit theory. The total volume of gas hydrate estimated, in an area of about 600 km 2 , is in a range of 16 × 10 9 -20 × 10 9 m 3 . Assuming that 1 m 3 of gas hydrate corresponds to 140 m 3 of free gas in standard conditions, the reservoir could contain a total volume that ranges from 1.68 to 2.8 × 10 12 m 3 of free gas. The interpretation of the pre-stack depth migrated sections and the high resolution morpho-bathymetry image allowed us to define a structural model of the area. Two main fault systems, characterized by left transtensive and compressive movement, are recognized, which interact with a minor transtensive fault system. The regional geothermal gradient (about 37.5 °C/km), increasing close to a mud volcano likely due to fluid-upwelling, was estimated through the depth of the bottom simulating reflector by seismic data.