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In this study one seismic section offshore Chiloé Island was analyzed to better define the seismic character of the hydrate-bearing sediments. The velocity analysis was used to estimate the gas-phase concentration and relate it to the geological features. The velocity model allowed us to recognize two important layers that characterize hydrate-and free gas-bearing sediments above and below the BSR respectively: one located above the BSR, characterized by high velocity (1,800-2,200 m/s) and a second one, below the BSR, characterized by low velocity (1,600-1,700 m/s). A weak ref lector at about 100 m below the BSR marks the base of the second layer. AVO analysis and offset stack sections confirming that the reflector interpreted as BGR is related to free gas presence in the pore space. The velocity field is affected by lateral variation, showing maximum (above the BSR) and minimum (below the BSR) values in the sector. Here, the highest gas hydrate and free gas concentrations were calculated, obtaining 9.5% and 0.5% of total volume respectively. A variable BSR depth (from 300 to 600 mbsf) can be justified supposing a variable geothermal gradient (from 25 to 45 °C/km).

Recent studies have reported cold seeps offshore of Mocha Island. Gas hydrate occurrences along the Chilean margin could explain seeps presence. Gas-phase (gas hydrate and free gas) and geothermal gradients were estimated analysing two seismic sections. Close to Mocha Island (up to 20 km) were detected high (up to 1900 m/s) and low (1260 m/s) velocities associated with high gas hydrate (up to 20% of total volume) and free gas (up to 1.1% of total volume) concentrations, respectively. A variable and high geothermal gradient (65-110 • C/km) was obtained. These results are related to high supply of deep fluids canalised by faults and fractures. Faraway from Mocha Island (>60 km), free gas concentrations decrease to 0.3% of total volume and low geothermal gradient (from 35 to 60 • C/km) are associated with low fluids supply. Finally, we propose gas hydrate dissociation processes as the main supply source for seeps in the vicinity of Mocha Island. These processes can be caused by: (a) active faults and seismic activity; and (b) warm fluid expulsion from deeper zones altering hydrate stability conditions. In both cases, gas hydrate dissociation could generate slope instability and landslides, as occurred in the past in this region and reported in the literature.Energies 2018, 11, 3062 2 of 13 close to 3000 km (from 33 • S until 56 • S). In the second case, some authors have modelled possible scenarios for gas hydrate dissociation in shallow water (from 150 to 600 m water depth) considering the increasing temperature due to the global warming and the consequent potential methane release into the atmosphere. They concluded that the gas hydrate dissociation processes are induced just by a slight increment of temperature [25][26][27][28][29][30][31]. In this context, gas hydrate estimates contribute to evaluate submarine geohazards, global warming contribution related to gas hydrate dissociation and the potential methane reservoir. Moreover, estimates of methane stored in marine sediments as gas hydrate and free gas phases can be used to model more realistic scenarios associated with gas hydrates dissociation and its effects as a greenhouse gas.Relationships between gas hydrates and cold seeps have been documented in active and passive margins [5,[31][32][33][34][35][36], in which chemosynthetic communities, authigenic carbonate nodules, enrichment stable isotopes in pore water, and faults and fractures, connected with BSR and detected in seismic profiles, can be related to gas hydrate presence.The present study adds new information regarding gas-phase concentrations of the southern Chilean margin by using seismic and theoretical velocity models (Figure 1). Mocha Island is characterised by active seismicity and constitutes an emerged block uplifted during the Quaternary in the Arauco peninsula [37,38]. Further, Mocha Island is known for intertidal and subtidal gas seepage system [39,40] and deeper seeps at 1400 water depth [41], whose presence probably is related to gas hydrates dissociation. In this context, gas-phase est...

Large amounts of gas hydrate are present in marine sediments offshore Taitao Peninsula, near the Chile Triple Junction. Here, marine sediments on the forearc contain carbon that is converted to methane in a regime of very high heat flow and intense rock deformation above the downgoing oceanic spreading ridge separating the Nazca and Antarctic plates. This regime enables vigorous fluid migration. Here, we present an analysis of the spatial distribution, concentration, estimate of gas-phases (gas hydrate and free gas) and geothermal gradients in the accretionary prism, and forearc sediments offshore Taitao (45.5°–47° S). Velocity analysis of Seismic Profile RC2901-751 indicates gas hydrate concentration values <10% of the total rock volume and extremely high geothermal gradients (<190 °C·km−1). Gas hydrates are located in shallow sediments (90–280 m below the seafloor). The large amount of hydrate and free gas estimated (7.21 × 1011 m3 and 4.1 × 1010 m3; respectively), the high seismicity, the mechanically unstable nature of the sediments, and the anomalous conditions of the geothermal gradient set the stage for potentially massive releases of methane to the ocean, mainly through hydrate dissociation and/or migration directly to the seabed through faults. We conclude that the Chile Triple Junction is an important methane seepage area and should be the focus of novel geological, oceanographic, and ecological research.

In the last few years, interest in the offshore Chilean margin has increased rapidly due to the presence of gas hydrates. We have modelled the gas hydrate stability zone off Chilean shores (from 33° S to 46° S) using a steady state approach to evaluate the effects of climate change on gas hydrate stability. Present day conditions were modelled using published literature and compared with available measurements. Then, we simulated the effects of climate change on gas hydrate stability in 50 and 100 years on the basis of Intergovernmental Panel on Climate Change and National Aeronautics and Space Administration forecasts. An increase in temperature might cause the dissociation of gas hydrate that could strongly affect gas hydrate stability. Moreover, we found that the high seismicity of this area could have a strong effect on gas hydrate stability. Clearly, the Chilean margin should be considered as a natural laboratory for understanding the relationship between gas hydrate systems and complex natural phenomena, such as climate change, slope stability and earthquakes.

Two sectors, Itata and Valdivia, which are located in the Chilean margin were analysed by using seismic data with the main purpose to characterize the gas hydrate concentration. Strong lateral velocity variations are recognised, showing a maximum value in Valdivia offshore (2380 ms −1 above the BSR) and a minimum value in the Itata offshore (1380 m·s −1 below the BSR). In both of the sectors, the maximum hydrate concentration reaches 17% of total volume, while the maximum free gas concentration is located Valdivia offshore (0.6% of total volume) in correspondence of an uplift sector. In the Itata offshore, the geothermal gradient that is estimated is variable and ranges from 32 • C·km −1 to 87 • C·km −1 , while in Valdivia offshore it is uniform and about 35 • C·km −1 . When considering both sites, the highest hydrate concentration is located in the accretionary prism (Valdivia offshore) and highest free gas concentration is distributed upwards, which may be considered as a natural pathway for lateral fluid migration. The results that are presented here contribute to the global knowledge of the relationship between hydrate/free gas presence and tectonic features, such as faults and folds, and furnishes a piece of the regional hydrate potentiality Chile offshore.