The detailed characterization of solution‐derived nickel (II) oxide (NiO) hole‐transporting layer (HTL) films and their application in high efficiency organic photovoltaic (OPV) cells is reported. The NiO precursor solution is examined in situ to determine the chemical species present. Coordination complexes of monoethanolamine (MEA) with Ni in ethanol thermally decompose to form non‐stoichiometric NiO. Specifically, the [Ni(MEA)2(OAc)]+ ion is found to be the most prevalent species in the precursor solution. The defect‐induced Ni3+ ion, which is present in non‐stoichiometric NiO and signifies the p‐type conduction of NiO, as well as the dipolar nickel oxyhydroxide (NiOOH) species are confirmed using X‐ray photoelectron spectroscopy. Bulk heterojunction (BHJ) solar cells with a polymer/fullerene photoactive layer blend composed of poly‐dithienogermole‐thienopyrrolodione (pDTG‐TPD) and [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM) are fabricated using these solution‐processed NiO films. The resulting devices show an average power conversion efficiency (PCE) of 7.8%, which is a 15% improvement over devices utilizing a poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) HTL. The enhancement is due to the optical resonance in the solar cell and the hydrophobicity of NiO, which promotes a more homogeneous donor/acceptor morphology in the active layer at the NiO/BHJ interface. Finally, devices incorporating NiO as a HTL are more stable in air than devices using PEDOT:PSS.
Interface recombination induced by the defect states in zinc‐oxide‐nanoparticle‐based electron extraction layer is reported as a significant loss‐mechanism of photocurrent collection. By choosing appropriate UV–ozone treatment conditions on the zinc oxide layer, inverted polymer solar cells show reduced interface recombination and thus improved power conversion efficiencies of up to 8.1%.
Infrared, visible, and multispectral photodetectors are important components for sensing, security and electronics applications. Current fabrication of these devices is based on inorganic materials grown by epitaxial techniques which are not compatible with low‐cost large‐scale processing. Here, air‐stable multispectral solution‐processed inorganic double heterostructure photodetectors, using PbS quantum dots (QDs) as the photoactive layer, colloidal ZnO nanoparticles as the electron transport/hole blocking layer (ETL/HBL), and solution‐derived NiO as the hole transport/electron blocking layer (HTL/EBL) are reported. The resulting device has low dark current density of 20 nA cm‐2 with a noise equivalent power (NEP) on the order of tens of picowatts across the detection spectra and a specific detectivity (D*) value of 1.2 × 1012 cm Hz1/2 W‐1. These parameters are comparable to commercially available Si, Ge, and InGaAs photodetectors. The devices have a linear dynamic range (LDR) over 65 dB and a bandwidth over 35 kHz, which are sufficient for imaging applications. Finally, these solution‐processed inorganic devices have a long storage lifetime in air, even without encapsulation.
The VOC loss in several polymer-fullerene solar cells is determined. Based on these data, a major source of photovoltage loss is attributed to the low dielectric constants of the polymers. Such loss is close to zero if the dielectric constant of the polymer-fullerene blend is close to 5.
Commercially available near-infrared (IR) imagers are fabricated by integrating expensive epitaxial grown III-V compound semiconductor sensors with Si-based readout integrated circuits (ROIC) by indium bump bonding which significantly increases the fabrication costs of these image sensors. Furthermore, these typical III-V compound semiconductors are not sensitive to the visible region and thus cannot be used for multi-spectral (visible to near-IR) sensing. Here, a low cost infrared (IR) imaging camera is demonstrated with a commercially available digital single-lens reflex (DSLR) camera and an IR sensitive organic light emitting diode (IR-OLED). With an IR-OLED, IR images at a wavelength of 1.2 µm are directly converted to visible images which are then recorded in a Si-CMOS DSLR camera. This multi-spectral imaging system is capable of capturing images at wavelengths in the near-infrared as well as visible regions.
Since being introduced to the open literature in 2010, the isoindigo heterocycle has been extensively studied as a novel electron-deficient building block for organic electronic materials in conjugated polymers, discrete length oligomers, and molecular systems, particularly targeting high charge mobility values and ambipolar transport in organic field effect transistors, along with high power conversion efficiencies in organic photovoltaic devices. This article introduces results obtained on copolymers of isoindigo with thiophene and alkylated terthiophenes to highlight fundamental characteristics in isoindigo-based polymers and the resulting organic field-effect transistors and photovoltaic devices. By comparing and contrasting the optoelectronic properties, thin film morphology, organic field-effect transistor (OFET) mobilities, and organic photovoltaic (OPV) performance to previously reported polymers, structure–processing–property relationships were uncovered. In particular, isoindigo-containing polymers with more rigid backbones and higher coherence lengths in thin films lead to increased charge mobility in OFET devices. In OPV devices, efficiencies over 6% can be obtained by balancing high ionization potentials typically dictating the open-circuit voltage and the charge transfer energy, and blend morphology impacting short-circuit currents. Furthermore, the impact of polymer structure on solubility and on phase separation in blends with PC71M is discussed, with isoindigo-based polymers exhibiting lower solubility possibly leading to more fiber-like morphologies stemming either from polymer dissolution in the casting solvent or from polymer self-assembly during film formation. This fiber-like polymer morphology remains unaffected by the presence of processing additives, such as 1,8-diiodooctane. These structure–property relationships developed for isoindigo-based polymers can also be discussed in the broader context of diketopyrrolopyrrole (DPP) and thienoisoindigo (TiI) as electron-deficient moieties that can also be doubly substituted on their amide functionality.
The effects of the oligothiophene length of two thiophene-isoindigo copolymers on film morphology, charge transfer, and photovoltaic device performance are reported. Despite the similarities in their repeat unit structures, the two polymers show distinctly different film morphologies and photovoltaic performance upon blending with PC71BM. We found that there is a significant increase in the dielectric constant of the photoactive film upon blending fullerene with the polymer that exhibits a higher power conversion efficiency. Blend photoluminescence transients revealed a fast dissociation route in the better performing polymer followed by a slower decay. The fast decay in transient PL is attributed to a higher charge transfer efficiency when blending with the fullerene. We suggest that the charge transfer efficiency is determined not only by the microscopic morphology but also whether the polymer can accommodate the fullerene molecules in close proximity to the acceptor moiety to facilitate electronic coupling between the isoindigo acceptor and the fullerene molecule. We propose that the fast decay component seen in transient PL for the better performing polymer, along with the increase in dielectric constant, is a signature of enhanced electronic coupling between the polymer and the fullerene. The enhanced electronic coupling is thought to originate from a polymer chemical structure which allows the fullerene molecules to come to closer proximity for more efficient charge transfer.
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