We report an approach to the development of advanced structural composites based on engineered multiscale carbon nanotube-carbon fiber reinforcement. Electrophoresis was utilized for the selective deposition of multi- and single-walled carbon nanotubes (CNTs) on woven carbon fabric. The CNT-coated carbon fabric panels were subsequently infiltrated with epoxy resin using vacuum-assisted resin transfer molding (VARTM) to fabricate multiscale hybrid composites in which the nanotubes were completely integrated into the fiber bundles and reinforced the matrix-rich regions. The carbon nanotube/carbon fabric/epoxy composites showed approximately 30% enhancement of the interlaminar shear strength as compared to that of carbon fiber/epoxy composites without carbon nanotubes and demonstrate significantly improved out-of-plane electrical conductivity.
The effect of nanotube/nanotube contact resistance on the electrical conductivity of carbon nanotube–based nanocomposites is studied. The tunneling resistance due to an insulating film of matrix material between crossing nanotubes is calculated by assuming a rectangular potential barrier in the insulating film. Monte Carlo simulations indicate that the tunneling resistance plays a dominant role in the electrical conductivity of composites, and the maximum tunneling distance is found to be about 1.8nm. Electrical conductivities of composites with inplane random distributions of carbon nanotubes follow the scaling law and the critical exponent depends on the level of contact resistance.
Developments in producing nanostructured materials with novel properties have opened up new opportunities in which unique functionality can be added to existing material systems. As advanced fiber composites are utilized more frequently in primary structural applications there is a key challenge to enhance the performance and reliability while reducing maintenance. As a consequence there is tremendous scientific and technical interest in the development of techniques for monitoring the health of composite structures where real-time sensing can provide information on the state of microstructural damage. In this research we utilize electrically conductive networks of carbon nanotubes as in situ sensors for detecting damage accumulation during cyclic loading of advanced fiber composites. Here we show that, by combining load and strain measurements in real-time with direct current electrical resistance measurements of the carbon nanotube network, insight can be gained toward the evolution and accumulation of damage. The resistance/strain relations show substantial hysteresis due to the formation and opening/closing of cracks during cyclic loading. Through interpreting the resistance response curves we identify a parameter that may be utilized as a quantitative measure of damage.
The emergence of stretchable electronic devices has attracted intensive attention. However, most of the existing stretchable electronic devices can generally be stretched only in one specific direction and show limited specific capacitance and energy density. Here, we report a stretchable isotropic buckled carbon nanotube (CNT) film, which is used as electrodes for supercapacitors with low sheet resistance, high omnidirectional stretchability, and electro-mechanical stability under repeated stretching. After acid treatment of the CNT film followed by electrochemical deposition of polyaniline (PANI), the resulting isotropic buckled acid treated CNT@PANI electrode exhibits high specific capacitance of 1147.12 mF cm(-2) at 10 mV s(-1). The supercapacitor possesses high energy density from 31.56 to 50.98 μWh cm(-2) and corresponding power density changing from 2.294 to 28.404 mW cm(-2) at the scan rate from 10 to 200 mV s(-1). Also, the supercapacitor can sustain an omnidirectional strain of 200%, which is twice the maximum strain of biaxially stretchable supercapacitors based on CNT assemblies reported in the literature. Moreover, the capacitive performance is even enhanced to 1160.43-1230.61 mF cm(-2) during uniaxial, biaxial, and omnidirectional elongations.
This book addresses the issue of designing the microstructure of fiber composite materials in order to obtain optimum performance. Besides the systematic treatment of conventional continuous and discontinuous fiber composites, the book also presents the state-of-the-art of the development of textile structural composites as well as the nonlinear elastic finite deformation theory of flexible composites. The author's experience during twenty years of research and teaching on composite materials is reflected in the broad spectrum of topics covered, including laminated composites, statistical strength theories of continuous fiber composites, short fiber composites, hybrid composites, two- and three-dimensional textile structural composites and flexible composites. This book provides the first comprehensive analysis and modeling of the thermo-mechanical behavior of fiber composites with these distinct microstructures. Overall, the inter-relationships among the processing, microstructures and properties of these materials are emphasized throughout the book. The book is intended as a text for graduate or advanced undergraduate students, but will also be an excellent reference for all materials scientists and engineers who are researching or working with these materials.
This letter studies the promising application of carbon nanotubes as nanoresonators. Both single- and double-walled carbon nanotubes are considered and the significant difference in the vibration behavior between them has been identified. The individual tube wall is treated as frame-like structures and simulated by the molecular-structural-mechanics method. The interlayer van der Waals interactions are represented by Lennard–Jones potential and simulated by a nonlinear truss rod model. The results show that fundamental frequencies of double-walled carbon nanotubes are about 10% lower than those of single-walled carbon nanotubes of the same outer diameter. The noncoaxial vibration of double-walled nanotubes begins at the third resonant frequency and does not significantly diminish the value of double-walled nanotubes as high-frequency nanoresonators.
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