We report a detailed study on the IR spectroscopy of HCl-water complexes in superfluid helium nanodroplets in the frequency range from 2660 to 2675 cm(-1). We have recorded spectra of HCl-H2(16)O as well as of HCl-H2(18)O complexes and compared these results with theoretical predictions. In addition, we have carried out mass-selective intensity measurements as a function of partial pressure of HCl as well as of H2(18)O (pick-up curves). The results support a scenario where the IR-absorption in this part of the spectrum contains contributions from undissociated as well as from dissociated clusters with Cl(-)(H2O)3(H3O)(+) being the smallest dissociated complex. These findings are corroborated by additional electric field measurements yielding the orientation of the vibrational transition moment with respect to the permanent dipole moment. As a result we are able to assign a broad absorption band starting at 2675 cm(-1) to dissociated HCl-water clusters (HCl)1(H2O)n with n ≥ 4. The two narrow absorption lines at 2667.9 cm(-1) and 2670 cm(-1) are assigned to an undissociated cluster, in agreement with previous studies.
Wall temperature measurements with fiber coupled online phosphor thermometry were, for the first time, successfully performed in a full scale H-class Siemens gas turbine combustor. Online wall temperatures were obtained during high-pressure combustion tests up to 8 bar at the Siemens CEC test facility. Since optical access to the combustion chamber with fibers being able to provide high laser energies is extremely challenging, we developed a custom-built measurement system, consisting of a water-cooled fiber optic probe and a mobile measurement container. A suitable combination of chemical binder and thermographic phosphor was identified for temperatures up to 1800 K on combustor walls coated with a thermal barrier coating (TBC). To our knowledge these are the first measurements reported with fiber coupled online phosphor thermometry in a full scale highpressure gas turbine combustor. Details of the setup and the measurement procedures will be presented. The measured signals were influenced by strong background emissions, probably from CO*2 chemiluminescence. Strategies for correcting backgroundemissions and data evaluation procedures are discussed. The presented measurement technique enables detailed study of combustor wall temperatures and using this information an optimization of the gas turbine cooling design.
The distinct optical properties of solid and liquid silicon nanoparticles are exploited to determine the distribution of gas-borne solid and liquid particles in situ using line-of-sight attenuation measurements carried out across a microwave plasma reactor operated at 100 mbar. The ratio between liquid and solid particles detected downstream of the plasma varied with measurement location, microwave power, and flow rate. Temperatures of the liquid particles were pyrometrically-inferred using a spectroscopic model based on Drude theory. The phase-sensitive measurement supports the understanding of nanoparticle formation and interaction and thus the overall gas-phase synthesis process.
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