A single-step hydrothermal route for synthesizing molybdenum doped zinc oxide nanoflakes was employed to accomplish superior electrochemical characteristics, such as a specific capacitance of 2296 F g À1 at current density of 1 A g À1 and negligible loss in specific capacitance of 0.01025 F g À1 after each chargedischarge cycle (up to 8000 cycles). An assembled asymmetric supercapacitor (Mo:ZnO@NF//AC@NF) also exhibited a maximum energy density and power density of 39.06 W h/kg and 7425 W kg À1 , respectively. Furthermore, it demonstrated a specific capacitance of 123 F g À1 at 1 A g À1 and retained about 75.6% of its initial capacitance after 8000 cycles. These superior electrochemical characteristics indicate the potential of this supercapacitor for next-generation energy storage devices.
Recently, there has been considerable interest in a new family of transition metal carbides, carbonitrides, and nitrides referred to as MXenes (Ti3C2Tx) due to the variety of their elemental compositions and surface terminations that exhibit many fascinating physical and chemical properties. As a result of their easy formability, MXenes may be combined with other materials, such as polymers, oxides, and carbon nanotubes, which can be used to tune their properties for various applications. As is widely known, MXenes and MXene-based composites have gained considerable prominence as electrode materials in the energy storage field. In addition to their high conductivity, reducibility, and biocompatibility, they have also demonstrated outstanding potential for applications related to the environment, including electro/photocatalytic water splitting, photocatalytic carbon dioxide reduction, water purification, and sensors. This review discusses MXene-based composite used in anode materials, while the electrochemical performance of MXene-based anodes for Li-based batteries (LiBs) is discussed in addition to key findings, operating processes, and factors influencing electrochemical performance.
For economical water splitting and degradation of toxic organic dyes, the development of inexpensive, efficient, and stable photocatalysts capable of harvesting visible light is essential.
In this study Cu-chitosan nanoparticles (Cu-CNP) have been employed as eco-friendly and safer priming agents to induce salt and PEG-induced hyperosmotic stress tolerance in wheat seedlings. Seed priming is a facile on-farm stress management technique that requires a little amount of priming agent and minimizes the eco-toxicological effects on soil fertility. The wheat seeds were primed with 0.12% and 0.16% Cu-CNP for eight hours and were allowed to germinate under normal, PEG-induced hyperosmotic stress (15% PEG-6000 – 3.0 Mpa) and salt stress (150 mM). For comparison, non-primed and hydro-primed seeds were also allowed to germinate as control under the same conditions. The biochemical analyses suggested the priming treatments enhanced the POD activity under salt stress but it was decreased under PEG-induced hyperosmotic stress. Priming with 0.12% Cu-CNP induced a significant increase in CAT while the opposite effect was observed in 0.16% treated seedling under stress and non-stress conditions. Both priming treatments did not allow the over-expression of SOD under both stress conditions. The total phenolic contents were also decreased significantly under all conditions. Except for priming with 0.16% Cu-CNP under PEG-induced hyperosmotic stress, a suppression in MDA was observed under both stress conditions. Surprisingly, the Cu-CNP priming induced a significant increase in β-carotenoids, total carotenoids, chlorophyll a, b and total chlorophyll under normal and stress conditions. In conclusion, the controlled expression of enzymatic antioxidants, low contents of non-enzymatic antioxidants and suppression of MDA mirror the stress mitigating role of Cu-CNP against PEG-induced hyperosmotic stress and salinity. The stress-insulating potential has also been reinforced by the enhanced production of plant and photosynthetic pigments. All these priming-induced biochemical changes produced positive effects on growth and germinating parameters in wheat seedlings under PEG-induced hyperosmotic stress as well as salinity.
In recent years, electrospinning has emerged as a promising technique for the preparation of nanofibers with unique properties like flexibility, high porosity and high surface area. In the context of nanodelivery systems, polymer-based nanofibers have become promising carriers of drugs and bioactive compounds ensuring their sustained release and targeted delivery. In this study, neem extract-loaded nanofibers were developed as sustained delivery systems using the electrospinning method. The chitosan, alginate and polyethylene oxide were used as the polymeric matrix for loading of aqueous extract of neem leaves. The prepared nanofibers NF1, NF2 and NF3 carrying 2%, 4% and 6% extract respectively were characterized using SEM, FTIR, XRD and TGA. Further, the as-prepared nanocomposites exhibited a high degree of swelling and dual-phase release of phytoconstituents. Moreover, the developed controlled delivery systems were tested for antifungal and antioxidant potential. Importantly, the bioactivities of the prepared nanofibers could be improved further by using organic extracts which are generally enriched with phytoconstituents. Herein, we selected biodegradable and mucoadhesive biopolymers and an aqueous extract of neem for the development of controlled-delivery nanofibers by electrospinning through a sustainable and cleaner production process. Thus, the prepared biocompatible nanofibrous systems with biphasic release profile could be employed for biomedical applications including wound dressing, soft tissue scaffolds and as transdermal carriers.
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