TiFe x Co 1 − x Sb half-Heusler materials with randomly distributed TiO2 particles have been synthesized by arc melting and annealing. Thermoelectric properties were measured in the temperature range of ∼300–850 K. TiCoSb shows n-type conduction, while TiFexCo1−xSb transfers to p-type conduction when x≥0.01. The electrical conductivity of p-type TiFexCo1−xSb increased with increasing Fe content. The maximum Seebeck coefficient reached about 300 μV/K at 850 K for x=0.15. Since Fe powder contained a trace of Fe2O3, a small amount of TiO2 particles formed during the synthesis process. The lattice thermal conductivity dramatically decreased with increasing Fe content, which was mostly caused by the introduction of in situ formed TiO2 particles, as well as the effects of mass fluctuation and strain field fluctuation due to the substitution of Fe to the Co site. The dimensionless figure of merit (ZT=S2σT/κ) was significantly improved over the whole temperature region, and a maximum ZT value of 0.45 has been obtained for the composition of TiFe0.15Co0.85Sb at 850 K.
Highly flat, clean, and stable surfaces of as-prepared Nd1Ba2Cu3Oy (Nd123) single crystals have been studied using an ultrahigh vacuum scanning tunneling microscope/spectroscopy (UHV-STM/STS) system. The results of large area STM scans together with the results of STS measurements, magnetization loops measured at several temperatures below Tc, and critical current density measurements reveal the presence of a new magnetic flux pinning center in Nd123 single crystals prepared in a reduced oxygen partial pressure. This pinning center is more conductive on the surface than the matrix and has a size ranging from several to several tens of nanometers as seen by STM. Similar pinning center may be introduced to other high temperature superconductors to increase their critical current densities in an applied magnetic field.
A novel PEGylation polypeptide, poly(ethylene glycol)-b-poly(l-lysine)-b-poly(l-cysteine) (PEG-PLL-PCys) triblock copolymer is synthesized via the sequential ring-opening polymerization of amino acid N-carboxyanhydrides initiated by methoxypolyethylene glycol amine (mPEG-NH , M is 2 kDa). Subsequently, the obtained polypeptide is partially conjugated with fluorocarbon chains via disulfide exchange reaction. PLL segment can condense plasmid DNA through an electrostatic force to form a complex core, PEG segment surrounding the complex like a corona can prevent the complex from precipitation and reduce the adsorption of serum, while PCys segment with fluorocarbon can enhance the cellular uptake and the stability of the formed polyplex micelles in physiological conditions. Experiment results exhibit that the fluorinated polypeptides have low cytotoxicity and good gene transfection efficiency even in the presence of 50% fetal bovine serum.
The dispersion of viral droplets plays a key role in the transmission of COVID-19. In
this work, we analyze the dispersion of cough-generated droplets in the wake of a walking
person for different space sizes. The air flow is simulated by solving the
Reynolds-averaged Navier–Stokes equations, and the droplets are modeled as passive
Lagrangian particles. Simulation results show that the cloud of droplets locates around
and below the waist height of the manikin after 2 s from coughing, which indicates that
kids walking behind an infectious patient are exposed to higher transmission risk than
adults. More importantly, two distinct droplet dispersion modes occupying significantly
different contamination regions are discovered. A slight change of space size is found
being able to trigger the transition of dispersion modes even though the flow patterns are
still similar. This shows the importance of accurately simulating the air flow in
predicting the dispersion of viral droplets and implies the necessity to set different
safe-distancing guidelines for different environments.
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