m-Xylylene bismaleimide, Compimide † MXBI (hereafter MXBI), was developed as a building block for formulating bismaleimide resins with improved processability. MXBI on its own, or in combination with 4,4′bismaleimidodiphenylmethane (Compimide MDAB, hereafter MDAB) and with 2,2′-diallylbisphenol-A as a comonomer, provides very low-melting resin blends, which can be processed at temperatures around 60-80°C via RTM (Resin Transfer Moulding), VARIM (Vacuum Assisted Resin Infusion Moulding), prepregging, and wet filament winding (FW). Uncured and cured resin properties were evaluated. The mechanical property spectrum of the MXBI/MDAB/diallylbisphenol-A system with varying MXBI/MDAB ratio shows almost equivalent contributions of MXBI and MDAB to the mechanical properties of a system. Higher MXBI proportions are responsible for lower resin viscosities and hence superior processability.
A novel low-melting, low-viscosity, one-part bismaleimide resin based on m-xylylene bismaleimide has been developed and examined for application in vacuum-assisted resin infusion. The resin is a fully formulated system comprising a ternary eutectic BMI mixture blended with bis-( o-propenylphenoxy)benzophenone and 2,2'-bis(3-allyl-4-hydroxyphenyl)propane as co-monomers. The resin offers enhanced properties for melt processing techniques. The formulation strategy and chemistry is presented and discussed in detail. For resin infusion and/or resin transfer molding technologies, the melt processing temperature of the resin is in the range of 90–110℃. Processing data of the uncured and mechanical properties of cured neat resin are provided. The resin shows a Tgof 285℃ when post-cured at 250℃ for 6 h. Finally, a 400 × 500 mm2carbon fabric laminate was successfully molded for demonstration by a VARI process. The microscopic study reveals no voids and no laminate surface imperfections. The VARI processing details are presented and discussed.
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