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Prompted by the scant attention paid by published literature reviews to the comprehensive catalytic dehydrogenative aromatization of cyclohexa(e)nones, this review describes recent methods developed to-date involving transition-metal-catalyzed oxidative aromatization and metal-free strategies for the transformation of cyclohexa(e)nones to substituted phenols.

A novel amino siloxane-functionalized MCM-41 supported Wells–Dawson type H6P2W18O62 (D-HPW) catalyst was synthesized by a two-step method and investigated in the gas phase dehydration of glycerol to acrolein, and the yield of acrolein was obviously improved.

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