BackgroundMechanical refining is a low-capital and well-established technology used in pulp and paper industry to improve fiber bonding for product strength. Refining can also be applied in a biorefinery context to overcome the recalcitrance of pretreated biomass by opening up the biomass structure and modifying substrate properties (e.g., morphology, particle size, porosity, crystallinity), which increases enzyme accessibility to substrate and improves carbohydrate conversion. Although several characterization methods have been used to identify the changes in substrate properties, there is no systematic approach to evaluate the extent of fiber cell wall disruption and what physical properties can explain the improvement in enzymatic digestibility when pretreated lignocellulosic biomass is mechanically refined. This is because the fiber cell wall is complex across multiple scales, including the molecular scale, nano- and meso-scale (microfibril), and microscale (tissue level). A combination of advanced characterization tools is used in this study to better understand the effect of mechanical refining on the meso-scale microfibril assembly and the relationship between those meso-scale modifications and enzymatic hydrolysis.ResultsEnzymatic conversion of autohydrolysis sugarcane bagasse was improved from 69.6 to 77.2% (11% relative increase) after applying mechanical refining and an increase in enzymatic digestibility is observed with an increase in refining intensity. Based on a combination of advanced characterizations employed in this study, it was found that the refining action caused fiber size reduction, internal delamination, and increase in pores and swellability.ConclusionsA higher level of delamination and higher increase in porosity, analyzed by TEM and DSC, were clearly demonstrated, which explain the faster digestibility rate during the first 72 h of enzymatic hydrolysis for disc-refined samples when compared to the PFI-refined samples. In addition, an increased inter-fibrillar distance between cellulose microfibrils at the nano–meso-scale was also revealed by SFG analysis, while no evidence was found for a change in crystalline structure by XRD and solid-state NMR analysis.
A comparison among ten market pulps at a laboratory scale using uncreped tissue handsheets was performed to study the performance of wood and non-wood pulps for tissue manufacturing, evaluate what fiber features are desired for a specific tissue property, and determine how non-wood pulps can be used to replace or complement wood pulps in tissue products. A characterization of the fiber morphology and handsheet properties (softness, water absorbency, and strength) was performed at different mechanical refining levels. The results showed that the fiber morphology had a major impact on tissue properties. Market pulps with a combination of long fibers, high coarseness, and low fines content can provide superior bulk and water absorbency. Short fibers with thin cell walls and low fines content can impart superior softness. Bleached bamboo soda pulp can replace hardwood and softwood pulps to provide an excellent combination of water absorbency and strength. Bleached bamboo soda pulp can also replace Northern bleached softwood kraft (NBSK) pulp to impart strength without sacrificing softness. Bleached and semi-bleached wheat straw soda pulps presented a similar combination of softness and strength as Southern bleached hardwood kraft (SBHK) pulp. The wheat straw pulps can be used to replace deinked pulp (DIP) pulp to impart intermediate levels of water absorbency and strength.
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