Microplastics accumulate in various aquatic organisms causing serious health issues, and have raised concerns about human health by entering our food chain. The recovery techniques for the most challenging colloidal fraction are limited, even for analytical purposes. Here we show how a hygroscopic nanocellulose network acts as an ideal capturing material even for the tiniest nanoplastic particles. We reveal that the entrapment of particles from aqueous environment is primarily a result of the network’s hygroscopic nature - a feature which is further intensified with the high surface area of nanocellulose. We broaden the understanding of the mechanism for particle capture by investigating the influence of pH and ionic strength on the adsorption behaviour. We determine the nanoplastic binding mechanisms using surface sensitive methods, and interpret the results with the random sequential adsorption (RSA) model. These findings hold potential for the explicit quantification of the colloidal nano- and microplastics from different aqueous environments, and eventually, provide solutions to collect them directly on-site where they are produced.

In nature, the protection of sensitive components from external threats relies on the combination of physical barriers and bioactive secondary metabolites. Polyphenols and phenols are active molecules that protect organisms from physical and chemical threats such as UV irradiation and oxidative stress. The utilization of biopolymers and natural bioactive phenolic components as protective coating layers in packaging solutions would enable easier recyclability of materials and greener production process compared with the current plastic-based products. Herein, we produce a fully wood-based double network material with tunable bioactive and optical properties consisting of nanocellulose and willow bark extract. Willow bark extract, embedded in nanocellulose, was cross-linked into a polymeric nanoparticle network using either UV irradiation or enzymatic means. Based on rheological analysis, atomic force microscopy, antioxidant activity, and transmittance measurements, the cross-linking resulted in a double network gel with enhanced rheological properties that could be casted into optically active films with good antioxidant properties and tunable oxygen barrier properties. The purely biobased, sustainably produced, bioactive material described here broadens the utilization perspectives for wood-based biomass, especially wood-bark extractives. This material has potential in applications where biodegradability, UV shielding, and antioxidant properties of hydrogels or thin films are needed, for example in medical, pharmaceutical, food, and feed applications, but also as a functional barrier coating in packaging materials as the hydrogel properties are transferred to the casted and dried films.

Foams are mainly composed of dispersed gas trapped in a liquid or solid phase making them lightweight and thermally insulating materials. Additionally, they are applicable for large surfaces, which makes them attractive for thermal insulation. State-of-the-art thermally insulating foams are made of synthetic polymeric materials such as polystyrene. This work focuses on generating foam from surfactants and renewable lignocellulosic materials for thermally insulating stealth material. The effect of two surfactants (sodium dodecyl sulphate (SDS) and polysorbate (T80)), two cellulosic materials (bleached pulp and nanocellulose), and lignin on the foaming and stability of foam was investigated using experimental design and response surface methodology. The volume-optimized foams determined using experimental design were further studied with optical microscopy and infrared imaging. The results of experimental design, bubble structure of foams, and observations of their thermal conductivity showed that bleached pulp foam made using SDS as surfactant produced the highest foam volume, best stability, and good thermal insulation. Lignin did not improve the foaming or thermal insulation properties of the foam, but it was found to improve the structural stability of foam and brought natural brown color to the foam. Both wet and dry lignocellulosic foams provided thermal insulation comparable to dry polystyrene foam. Graphical abstract

A semi-quantitative study of willow bark dye adsorption on two different cellulose materials using biomordants was carried out. The studied celluloses were microcrystalline cellulose (MCC) AaltoCell and regenerated Ioncell-F (IC) fibres. The dye was a hot water extract of willow bark and the adsorption to cellulose was carried out using carboxylic acid-containing biomordants, namely, oxalic acid, citric acid and tannic acid. Alum was employed as the reference mordant.A semi-quantitative estimation of the dye uptake was conducted using high-performance liquid chromatography equipped with a diode array detector and also by visual inspection, as well as an evaluation of the coloration using CIELab parameters. The mechanism of the dye adsorption on the cellulose surfaces was studied via Fourier Transform-infrared spectroscopy. According to the results, MCC had a higher affinity for polyphenolic dye than the regenerated cellulose fibres.Dye uptake on MCC was 50%-80% and 44%-57% on IC. For MCC, the biomordants improved the dye uptake more effectively than the control mordant, alum, whereas for IC the biomordants were less effective than alum.Päivi Laaksonen works as a principal research scientist at Häme University of Applied Sciences and leads a research team on long term durability of materials. She holds a M.Sc. (2005) and doctoral degree on physical chemistry and since the dissertation at Helsinki University of Technology (2008) she has worked as a senior scientist at VTT Technical Research Centre of Finland and as an assistant professor of materials science at Aalto University, Finland. Laaksonen has studied a wide range of self-assembling nanomaterials including, for instance, metal nanoparticles and biological macromolecules. Currently her interests are applications of biobased materials in technical and textile materials.This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. AbstractA semi-quantitative study of willow bark dye adsorption on two different cellulose materials using biomordants was carried out. The studied celluloses were microcrystalline cellulose (MCC) AaltoCell and regenerated Ioncell-F (IC) fibres. The dye was a hot water extract of willow bark and the adsorption to cellulose was carried out using carboxylic acid-containing biomordants, namely, oxalic acid, citric acid and tannic acid. Alum was employed as the reference mordant. A semi-quantitative

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Lignocellulosics, microalgae, and SDS were used to generate stable and colored wet foams intended for camouflage use. It was found that the addition of microalgae increased the foam stability. The hyperspectral and thermal properties were studied.