Beaches that are geologically controlled by rock and coral formations are the rule, not the exception. This paper reviews current understanding of geologically controlled beaches, bringing together a range of terminologies (including embayed beaches, shore platform beaches, relict beaches, and perched beaches among others) and processes, with the aim of exploring the multiple ways in which geology influences beach morphology and morphodynamics. We show how in addition to sediment supply, the basement geology influences where beaches will form by providing accommodation, and in the cross-shore, aspects of rock platform morphology such as elevation and slope are also important. Geologically controlled beaches can have significant variations in sediment coverage with seasons and storms, and geological controls have fundamental influences on their contemporary morphodynamics. This includes wave shadowing by headlands and rocky/coral formations inducing strong alongshore gradients in wave energy, resulting in corresponding variations in morphodynamic beach state and storm response. Geologically-induced rip currents such as shadow rips and deflection rips, and even mega-rips that can develop on embayed beaches during storms, are an integral feature of the nearshore circulation and morphodynamics of geologically controlled beaches. We bring these processes together by presenting a conceptual model of alongshore and cross-shore levels of geological control. In the longshore dimension, this ranges from beaches that are slightly embayed, through to highly embayed beaches where headlands dominate the entire beach morphodynamic response. In the cross-shore dimension, this ranges from beaches without discernible geological controls, through to relict beaches above the influence of the contemporary littoral zone. Given the prevalence of geologically controlled beaches along the world's coasts, it is paramount for coastal management to consider how these beaches differ from unconstrained beaches and avoid applying inappropriate models and tools, especially with our uncertain future climate.
<div> <div> <p> </p><div> <div> <div> <p>We present the CHAL336 benchmark set—the most comprehensive database for the assessment of chalcogen-bonding (CB) interactions. After careful selection of suitable systems and identification of three high-level reference methods, the set comprises 336 dimers each consisting of up to 49 atoms and covers both σ- and π-hole interactions across four categories: chalcogen-chalcogen, chalcogen-π, chalcogen-halogen, and chalcogen-nitrogen interactions. In a subsequent study of DFT methods, we re-emphasize the need for using proper London dispersion corrections when treating noncovalent interactions. We also point out that the deterioration of results and systematic overestimation of interaction energies for some dispersion-corrected DFT methods does not hint at problems with the chosen dispersion correction, but is a consequence of large density-driven errors. We conclude this work by performing the most detailed DFT benchmark study for CB interactions to date. We assess 109 variations of dispersion-corrected and -uncorrected DFT methods, and carry out a detailed analysis of 80 of them. Double-hybrid functionals are the most reliable approaches for CB interactions, and they should be used whenever computationally feasible. The best three double hybrids are SOS0-PBE0-2-D3(BJ), revDSD-PBEP86-D3(BJ), and B2NCPLYP-D3(BJ). The best hybrids in this study are ωB97M-V, PW6B95-D3(0), and PW6B95-D3(BJ). We do not recommend using the popular B3LYP functional nor the MP2 approach, which have both been frequently used to describe CB interactions in the past. We hope to inspire a change in computational protocols surrounding CB interactions that leads away from the commonly used, popular methods to the more robust and accurate ones recommended herein. We would also like to encourage method developers to use our set for the investigation and reduction of density-driven errors in new density functional approximations. </p> </div> </div> </div> </div> </div>
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