Collection : Chemistry and Materials ScienceInternational audienceIn the last few years, eco friendly materials have become an important part of the building materials market. Natural fibres are already used in various types of materials, like plastics, concrete and lime-based products. They demonstrate different attributes like the combination of good mechanical, thermal and acoustic properties that allow these types of materials to be used for different applications. The main drawback associated with plaster is its brittleness, especially under tensile stress. Therefore, it is interesting to investigate different methods that could potentially enhance the mechanical properties of plaster. Adding fibres to gypsum to obtain a composite material is one way to improve the behaviour of the product, especially after the failure of the matrix. The aim of this work was to the study the effects of adding natural fibres, namely hemp and flax fibres, on the setting time of plaster and the mechanical properties of the composite matrix. It was shown that hemp delayed the setting of plaster, unlike flax. The initial and final setting times almost doubled when hemp was added in a plaster matrix, whereas flax fibres did not drastically change them. Different chemical treatments of hemp were tested and the impact on the setting time was measured. The setting times of both composites made with hemp and flax were reduced once the fibres were treated (25-40% reduction), compared to the setting time of the calcium sulphate hemihydrate alone. The mechanical properties of the composite materials are also discussed. The behaviour of plaster was modified from brittle to a non-linear one when fibres were added, and even at small levels of addition, flax fibres allowed slightly higher values of flexural strength to be reached
Chemical reactivity of hemp fibres placed into a cimentitous matrix was studied by using a lime solution as a simplified cement solution. The hemp fibres contain 56.1 wt.% of cellulose, 20.1 wt.% of pectin, 10.9 wt.% of hemicellulose and 6 wt.% of lignin. These compounds are not solubilised in a basic medium rich in calcium but a part located at the fibre surface should be degraded. This treatment leads also to the decrease of the cristallinity index of the cellulose. Calcium ions adsorb in a large quantity onto the fibre surface due to the high concentration of pectin. The structure of the homogalacturonic part of pectin forms with Ca2+ a stable chelate called "egg-box", supporting cation adsorption. The fibres are then covered by Ca(OH)2 nodules after immersion in a lime solution
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