The authors conclude, from the work reported herein, that commercially available deresinated guayule rubber may best be compounded in the same manner as Hevea rubber, with an expectation of obtaining approximately 75 per cent of the tensile strength of a similar Hevea stock. It is concluded further that deresinated guayule rubber may generally be processed and cured in the same manner as Hevea rubber without sacrificing quality to a greater extent than is done with Hevea rubber.
Recently Werkenthin, Richardson, Thornley and Morris reported on the sunlight and accelerated light aging of various natural and synthetic rubber stocks, and proposed a method for standardizing the accelerated light aging test. The purpose of the present paper is to provide data on the correlation of sunlight aging with accelerated light aging for various synthetic rubber stocks loaded with mineral pigments. FORMULAS AND CURES The formulas and cures for the synthetic rubber stocks are given in Table I. These stocks have a loading corresponding to a good quality, 40 per cent wire insulation compound. Most of the prominent types of synthetic rubber manufactured in this country and one foreign synthetic rubber were included in this study. It was necessary to blend Vistanex Medium with natural rubber, inasmuch as this synthetic rubber cannot be vulcanized.
A survey has been made of hard GR-S with regard to sulfur requirement and effects of various pigments, softeners, and accelerators on tensile strength, ultimate elongation, hardness, and stiffness. Of particular interest where the observations that hard GR-S had a higher tensile strength than hard Hevea rubber, and that hard GR-S did not undergo much loss in tensile strength when compounded with 60 volumes of channel black or semi-reinforcing black.
The slow-bend brittle point test does not have the same practical significance as the Bell Telephone Laboratories brittle point test because most rubber articles which are exposed to low temperatures in service are required to withstand fairly rapid flexing. If the slow-bend brittle point test were used as a criterion of the cold resistance of these rubber articles, it might qualify the rubbers for a lower temperature than they could safely withstand in service. The brittle point test developed by the Bell Telephone Laboratories is simple and sensitive. It is believed that this test may advantageously be used to study all cold resistance problems where damage to the rubber itself and not increase in stiffness is the first consideration.
The method described herein for determining brittle point is relatively simple, and the results are indicative of the ability of the material to withstand impact combined with bending. It is believed that this combination will more correctly evaluate brittle point than a bent loop test or other moderate flexing tests. If the material is exposed to low ambient air temperatures in service, then tests to determine brittle point should be made in cold air and not in an immersion bath. Appreciable differences in brittle point are obtained by judicious modifications in compounding ingredients of Buna-N and chloroprene synthetic rubbers.
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