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We investigated the magnetic anisotropic parameters and spin-wave relaxation of thin films of the ferromagnetic half-metallic Sr2FeMoO6 by ferromagnetic resonance technique. The resonance field and linewidth were recorded as a function of relative angle between applied magnetic field and crystallographic axes of the sample. The resonance field varies sinusoidally and considerable linewidth broadening occurs when the applied field is rotated parallel to the sample plane. The results are described using higher order components of anisotropy fields. We obtain the values of the cubic anisotropic field, 2K4∥∕M=0.09611T, the effective demagnetization field, 4πM−2K2⊥∕M=0.1216T, and the planar anisotropic field, 2K4⊥∕M=−0.108T. Moreover, we estimated the spin relaxation time (damping factor) from the analysis of the angular dependence of peak-to-peak linewidth, leading to an intrinsic value of α∼0.00025 (Gilbert damping).

A scalable method for the fabrication of cathodes based on firing pristine compounds Li2MnO3 and LiMn0.33Ni0.33Co0.33O2 with LiCl molten flux is explored.

We study the quasiparticle relaxation dynamics in the electron-doped superconductor, BaFe1.85Co0.15As2 (BFCA) by using optical spectroscopy in both time and frequency domains. The estimate of the electron−phonon (el–ph) coupling constant from quasiparticle relaxation rate in time domain gives a value of ∼0.16 that is much too small to give a TC of 25 K. We obtain a negative value of the Coulomb pseudopotential that implies that the el−ph interaction alone is not strong enough to induce a superconducting transition in BFCA. More importantly, the electron-boson spectral function determined from optical scattering rate in frequency domain does not resemble the measured phonon density of states and has a dominant peak (at 53 meV) beyond the phonon frequencies. Our results support that the BFCA is a multi-gap s-wave superconductor and that its electron pairing is based on a spin-mediated pairing mechanism.

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LiMPO4 are orthorhombic crystals, belonging to the olivine family and exhibit exceptionally high applicability for electrochemical energy storage in lithium-ion secondary batteries due to their charge storage capacity, chemical and thermal stability, and cost. Furthermore, mixed transition metal ion compounds Li(M,M’)PO4 are particularly promising cathode materials because the redox voltage increases as from Fe to Mn, Ni, Co 1and the mixed compounds can be tailored for specific applications. The aim of these studies is to better understand the key role played by the transition metals such as Fe, Mn and particularly their mixtures in determining the properties of these materials. Single crystal 7Li and 31P NMR studies are used to obtain precise information on the magnetic environments of the lithium ions and phosphate groups which may ultimately be correlated with processes and structural features that determine the electrochemical behavior of these olivine phosphates. By measurements of 7Li and 31P NMR frequencies, i.e. ν = B0∙σ∙Ι, where B0 is the applied field and Ι is the nuclear spin, with crystal orientation, it is possible to determine interaction tensor components {σij } giving rise to the lithium and phosphorus shifts. The series of the single crystals of LiMPO4 were prepared by a reciprocal salt flux growth technique, which allows the facile preparation of single crystals up to 1 cm across with well-developed facets at relatively low temperatures. Crystals for the NMR measurements present their natural faceting2. X-ray diffraction measurements were performed in order to identify the principal crystallographic axes [100], [010] and [001] of the samples. Subsequently the crystals were fixed to a rigid insert in the NMR probe, which was mounted onto a goniometer and inserted between the gap of a permanent magnet (B0=2.1T). The use of a relatively low field strength allowed for acquisition of the entire rotation pattern within the spectrometer bandwidth. Rotations were made with the goniometer shaft perpendicular to applied magnetic field, in this way it was possible to generate 24 spectra, one every 15o, for each crystallographic axis [100],[010] and [001]. Previous studies3 showed that in the case of 31P, crystals exhibit large (paramagnetic) shifts on the order of 3000ppm, primarily due to the hyperfine interactions between the unpaired electron spins of the paramagnetic ion and the phosphorus nuclei. The 7Li resonances are also strongly affected by the paramagnetic susceptibility though not to the same extent as 31P. However in addition, there is a nuclear quadrupole interaction which splits the resonance and provides information concerning the electric field gradient In addition to the endpoints (Fe and Mn analogues), we present an NMR analysis of the mixed transition metal ion compounds LiFexMn1-xPO4 , where x = 0.25, 0.5, and 0.75 in order to shed some light on the degree of cation disorder between the lithium, phosphorus, and transition metal sites that can result in substantial degradation of cathode performance particularly with regard to reduced rate capability. This research was supported by the U.S. Department of Energy References: 1 K. Wang, A. Maljuk, C.G.F. Blum, T. Kolb, C. Jähne, C. Neef, H.J. Grafe, L. Giebeler, H. Wadepohl, H.P. Meyer, S. Wurmehl, R. Klingeler, Journal of Crystal Growth, Volume 386, 16(2014) 2 Y. Janssen, D. Santhanagopalan, D. Quian, M. Chi, X. Wang, C. Hoffmann, Y.S. Meng, P.G. Khalifah, Chem. Mater., DOI: 10.1021/cm4027682 Publication Date (Web): October 10, 2013 3 P.E. Stallworth, R. Samueli, P. Sideris, D. Vaknin, S.G. Greenbaum, Advances in Inorganic Phosphate Materials: Ceramic Transactions, Volume 233 (eds I. Belharouak and V. G. Pol), John Wiley & Sons, Inc., Hoboken, NJ, USA (2012)

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