Dried ground bagasse, impregnated with 50% inorganic acids and carbonized at 500°C, showed the sequence H3PO4 > H2SO4 > HCl > HNO3, with respect to the efficiency of activation. Treatment with phosphoric acid of various concentrations (30–50 wt%) was followed by carbonization at 300–500°C for 3 h. Pore structure parameters were determined from the low‐temperature adsorption of nitrogen, by applying the BET and αs methods. Activated carbons obtained at low temperatures are essentially microporous with a low degree of mesoporosity. At higher temperatures products of higher surface area and total pore volume with developed mesoporosity and low microporosity are formed. An increase in the period of carbonization leads to a small decrease in both surface area and pore volume. Activated carbons with surface areas > 1000 m2 g−1 and mean pore dimensions around 2·0 nm, suitable for various purposes, are thus obtained.
Activated carbons were prepared from olive oil solid wastes by treatment in different schemes: impregnation with H 3 PO 4 followed by pyrolysis at 300±700°C, by steam pyrolysis at 600± 700°C, or by conventional steam activation at 850°C. Porosity characteristics were determined by analysis of nitrogen adsorption isotherms, and carbons of widely different properties and surface pH values were obtained. Decomposition of H 2 O 2 in dilute unbuffered solution was followed by measuring evolved oxygen volumetrically. First-order kinetics was followed, and the catalytic rate coef®cients were evaluated. The carbons tested showed appreciable activity where evolved oxygen attained %10% of the stoichiometric amount in 1 h. The degree of decomposition showed inverse dependence on surface area, pore volume and mean pore dimensions. The chemical nature of the surface, rather than the porosity characteristics, was the principal factor in enhancing the disproportionation of H 2 O 2 on the activated carbon surface.
Locally discarded olive oil waste was tested as a potential raw material for the preparation of activated carbons. Chemical activation by impregnation with H3PO4 was employed using acid solutions of varying concentration in the range 30–70% followed by thermal treatment at 500–700°C. The development of porosity was followed from an analysis of the nitrogen adsorption isotherms obtained at 77 K by applying standard BET and t-plot methods. Carbons with low to moderate surface areas (273–827 m2/g) and total pore volumes (0.27–0.69 ml/g), containing essentially micropores with diameters of 8.2 Å up to 12.4 Å were obtained. Increasing the concentration of impregnant led to the development of porosity with the optimum being attained at 60% H3PO4. Phosphoric acid is visualized as acting both as an acid catalyst promoting bond-cleavage reactions and the formation of new crosslinks and also as a reactant which combines with organic species to form phosphate and polyphosphate bridges which connect and crosslink biopolymer fragments. The present study suggests many applications for environmental pollution control, firstly by utilizing accumulating low-cost agricultural by-products and secondly by producing a multi-purpose high-capacity adsorbent useful in the remediation of micropollutants in various water courses.
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