High ionic conductivity membranes can be used to minimize ohmic losses in electrochemical devices such as fuel cells, flow batteries, and electrolyzers. Very high hydroxide conductivity was achieved through the synthesis of a norbornene-based tetrablock copolymer with an ion-exchange capacity of 3.88 meq/g. The membranes were cast with a thin polymer reinforcement layer and lightly crosslinked with N,N,N ,N -tetramethyl-1,6-hexanediamine. The norbornene polymer had a hydroxide conductivity of 212 mS/cm at 80°C. Light cross-linking helped to control the water uptake and provide mechanical stability while balancing the bound (i.e. waters of hydration) vs. free water in the films. The films showed excellent chemical stability with <1.5% conductivity loss after soaking in 1 M NaOH for 1000 h at 80°C. The aged films were analyzed by FT-IR before and after aging to confirm their chemical stability. A H 2 /O 2 alkaline polymer electrolyte fuel cell was fabricated and was able to achieve a peak power density of 3.5 W/cm 2 with a maximum current density of 9.7 A/cm 2 at 0.15 V at 80°C. The exceptionally high current and power densities were achieved by balancing and optimizing water removal and transport from the hydrogen negative electrode to the oxygen positive electrode. High water transport and thinness are critical aspects of the membrane in extending the power and current density of the cells to new record values.
Stretchable electronics are emerging as a new technological advancement, since they can be reversibly stretched while maintaining functionality. To power stretchable electronics, rechargeable and stretchable energy storage devices become a necessity. Here, we demonstrate a facile and scalable fabrication of full stretchable supercapacitor, using buckled single-walled carbon nanotube macrofilms as the electrodes, an electrospun membrane of elastomeric polyurethane as the separator, and an organic electrolyte. We examine the electrochemical performance of the fully stretchable supercapacitors under dynamic stretching/releasing modes in different stretching strain rates, which reveal the true performance of the stretchable cells, compared to the conventional method of testing the cells under a statically stretched state. In addition, the self-discharge of the supercapacitor and the electrochemical behavior under bending mode are also examined. The stretchable supercapacitors show excellent cyclic stability under electrochemical charge/discharge during in situ dynamic stretching/releasing.
A high voltage (2 V) asymmetric stretchable supercapacitor based on two metal oxide/CNT electrodes with high electrochemical and dynamic mechanical cycling stability is presented.
Pseudocapacitors, which are energy storage devices that take advantage of redox reactions to store electricity, have a different charge storage mechanism compared to lithium-ion batteries (LIBs) and electric double-layer capacitors (EDLCs), and they could realize further gains if they were used as stretchable power sources. The realization of dynamically stretchable pseudocapacitors and understanding of the underlying fundamentals of their mechanical-electrochemical relationship have become indispensable. We report herein the electrochemical performance of dynamically stretchable pseudocapacitors using buckled MnO2/CNT hybrid electrodes. The extremely small relaxation time constant of less than 0.15 s indicates a fast redox reaction at the MnO2/CNT hybrid electrodes, securing a stable electrochemical performance for the dynamically stretchable pseudocapacitors. This finding and the fundamental understanding gained from the pseudo-capacitive behavior coupled with mechanical deformation under a dynamic stretching mode would provide guidance to further improve their overall performance including a higher power density than LIBs, a higher energy density than EDLCs, and a long-life cycling stability. Most importantly, these results will potentially accelerate the applications of stretchable pseudocapacitors for flexible and biomedical electronics.
Advanced electrode materials with bendability and stretchability are critical for the rapid development of fully flexible/stretchable lithium‐ion batteries. However, the sufficiently stretchable lithium‐ion battery is still underdeveloped that is one of the biggest challenges preventing from realizing fully deformable power sources. Here, a low‐temperature hydrothermal synthesis of a cathode material for stretchable lithium‐ion battery is reported by the in situ growth of LiMn2O4 (LMO) nanocrystals inside 3D carbon nanotube (CNT) film networks. The LMO/CNT film composite has demonstrated the chemical bonding between the LMO active materials and CNT scaffolds, which is the most important characteristic of the stretchable electrodes. When coupled with a wrinkled MnOx/CNT film anode, a binder‐free, all‐manganese‐based stretchable full battery cell is assembled which delivers a high average specific capacity of ≈97 mA h g−1 and stabilizes after over 300 cycles with an enormous strain of 100%. Furthermore, combining with other merits such as low cost, natural abundance, and environmentally friendly, the all‐manganese design is expected to accelerate the practical applications of stretchable lithium‐ion batteries for fully flexible and biomedical electronics.
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