A number of proposed next-generation electronic devices, including novel memory elements 1 and versatile transistor circuits 2 , rely on spin currents, that is, the flow of electron angular momentum. A spin current may interact with a magnetic nanostructure and give rise to spin-dependent transport phenomena, or excite magnetization dynamics 1-11 . In contrast to a spin-polarized charge current, a pure spin current does not produce any charge-related spurious effects 12,13 . One way to produce a pure spin current is non-local electrical-spin injection 12-18 , but this approach has suffered so far from low injection efficiency. Here, we demonstrate a significant enhancement of the non-local injection efficiency in a lateral spin valve prepared with an entirely in situ fabrication process. Improvements to the interface quality and the device structure lead to an increase of the spin-signal amplitude by an order of magnitude. The generated pure spin current enables the magnetization reversal of a nanomagnet with the same efficiency as in the case of using charge currents. These results are important for further theoretical developments in multiterminal structures 2 , but also with a view towards realizing novel devices driven by pure spin currents.In a vertical spin-valve nanopillar consisting of a ferromagnet/non-magnet/ferromagnet trilayer, the magnetic state can be switched between the antiparallel and the parallel configurations by applying a charge current [1][2][3][4][5][6][7][8][9][10][11] . This charge-current-induced magnetization switching (CIMS) is the result of a direct transfer of spin angular momentum from the spin current carried along the charge current to the localized magnetic moment in the ferromagnet. Separation of the charge and spin components raises the possibility of chargeless pure spin-current-induced magnetization switching (pure spin CIMS).The pure spin current transfers only spin angular momentum, and thus provides an attractive means to manipulate the magnetic state in magnetic nanostructures as well as a quiet electrical background for experimental studies. The pure spin current I S can be generated by the diffusion of the accumulated spins 12-20 in a metallic lateral spin-valve (LSV) structure with non-local electrical spin injection, as shown in Fig. 1a. When the spin accumulation at the interface between the permalloy (Py) and Cu wires on the detector side is non-collinear to the Py magnetization, the transverse component of the pure spin CuAu Py

Lysozyme monolayer-protected gold nanoparticles (Au NPs) which are hydrophilic and biocompatible and show excellent colloidal stability (at low temperature, ca. 4 degrees C), were synthesized in aqueous medium by chemical reduction of HAuCl4 with NaBH4 in the presence of a familiar small enzyme, lysozyme. UV-vis spectra, transmission electron microscopy (TEM), atomic force microscopy, and X-ray photoelectron spectroscopy characterization of the as-prepared nanoparticles revealed the formation of well-dispersed Au NPs of ca. 2 nm diameter. Moreover, the color change of the Au NP solution as well as UV-vis spectroscopy and TEM measurements have also demonstrated the occurrence of Ostwald ripening of the nanoparticles at low temperature. Further characterization with Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering indicated the formation of a monolayer of lysozyme molecules on the particle surface. FTIR data also indicated the intactness of the protein molecules coated on Au NPs. All the characterization results showed that the monodisperse Au NPs are well-coated directly with lysozyme. Driven by the dipole-dipole attraction, the protein-stabilized Au NPs self-assembled into network structures and nanowires upon aging under ambient temperature. On the basis of their excellent colloidal stability, controlled self-assembly ability, and biocompatible surface, the lysozyme monolayer-stabilized Au NPs hold great promise for being used in nanoscience and biomedical applications.

A large-scale lambda-DNA network on a mica surface was successfully fabricated with a simple method. Silver nanoparticles capped with the cationic surfactant cetyltrimethylammonium bromide (CTAB) were self-assembled onto a two-dimensional DNA network template by electrostatic interaction and formed nanoporous silver films, which can be used as active surface-enhanced raman scattering (SERS) substrates. Two probe molecules, Rhodamine 6G (R6G) and 4-aminothiophenol (4-ATP), were studied on these substrates with very low concentrations, and great enhancement factors for R6G (0.21 x 10(10)-4.09 x 10(11)) and 4-ATP (approximately 1.70 x 10(5)) were observed. It was found that the enhancement ability was affected by the DNA concentration and the electrostatic absorption time of the CTAB-stabilized silver nanoparticles on the DNA strands. These SERS substrates formed by the self-assembly of silver nanoparticles on DNA network also show good stability and reproducibility in our experiments.

Chemical diffusion and reaction rates are two general kinetic factors involved in the formation of materials. They play an important role in the structure development of materials. In most cases, chemical diffusion and reaction are coupled each other, which makes it difficult to differentiate their effects in shaping materials.Here we propose to quantify diffusion and reaction by the Damkoḧler number (Da) and to elucidate their roles in shaping particles. Silver particles are synthesized by electrodeposition approach at different reaction and diffusion conditions. Both diffusion efficiency and reaction rate constants are quantified, and the Damkoḧler number is calculated. If chemical diffusion or reaction is the rate-determining step in the formation of materials, simple structures, such as polyhedrons and irregular particles, are usually formed. When the interplay of diffusion and reaction dominates the structure development, complex structures, such as dendrites, are generated. The formation of each structure is closely related to Da values. On the basis of this finding, three growth modes of particles are put forward and evaluated by the following studies.

Flat-lying, densely packed DNA monolayers in which DNA chains are well organized have been successfully constructed on a mica surface by dropping a droplet of a DNA solution on a freshly cleaved mica surface and subsequently transferring the mica to ultrapure water for developing. The formation kinetics of such monolayers was studied by tapping mode atomic force microscopy (TMAFM) technique. A series of TMAFM images of DNA films obtained at various developing times show that before the sample was immersed into water for developing the DNA chains always seriously aggregated by contacting, crossing, or overlapping and formed large-scale networks on the mica surface. During developing, the fibers of DNA networks gradually dispersed into many smaller fibers up to single DNA chains. At the same time, the fibers or DNA chains also experienced rearrangement to decrease electrostatic repulsion and interfacial Gibbs free energy. Finally, a flat-lying, densely packed DNA monolayer was formed. A formation mechanism of the DNA monolayers was proposed that consists of aggregation, dispersion, and rearrangement. The effects of both DNA and Mg2+ concentration in the formation solution on DNA monolayer formation were also investigated in detail.

Current-induced magnetization excitations are studied for a spin-torque oscillator (STO) composed of a nanopillar with a perpendicular polarizer layer (PL), a MgO barrier layer, and a planar free layer (FL). By applying direct current and perpendicular-to-plane magnetic field, we measure resistance and radio-frequency electrical signal of the STO, which reflect magnetization motions of both PL and FL. Examination of the experimental results reveals that large-cone-angle magnetization oscillation occurs in the FL regardless of the current direction, whereas the PL magnetization shows principally either synchronized excitation with the FL oscillation or thermal-induced ferromagnetic resonance (FMR), depending on the current direction. Utilizing macrospin simulations, we show that hybridization of the excitation modes of the PL and FL through mutual dipolar field explains the magnetization dynamics. When the current flows from the PL to the FL, large-cone-angle oscillation of the FL magnetization occurs with the same rotation direction as that of FMR of the PL magnetization, leading to emergence of the synchronized excitation modes. On the other hand, when the current flows from the FL to the PL, the magnetization motions of the two layers have opposite rotation directions, and consequently, the PL and FL show their respective intrinsic excitation modes.

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We reported a simple method to synthesize gold nanoparticles (NPs) by photoreducing HAuCl 4 in acetic acid solution in the presence of type I collagen. It was found that the collagen takes an important role in the formation of gold NPs. The introduction of collagen made the shape of the synthesized gold nanocrystals change from triangular and hexangular gold nanoplates to size-uniform NPs. On the other hand, thanks to the special characters of collagen molecules, such as its linear nanostructure, are positively charged when the pH < 7, and the excellent self-assembly ability, photoreduced gold NPs were assembled onto the collagen chains and formed gold NPs films and networks. A typical probe molecule, 4-aminothiophenol, was used to test the surface-enhanced Raman scattering activity of these gold NPs films and networks and the results indicated good Raman activity on these substrates.