The detection of hazardous chemicals, explosives, improvised explosive materials, energetic materials and their associated compounds for security screening, forensic applications and detection of unexploded ordnance is an active area of research. The results based on comprehensive experimental study and performance of time gated Raman spectroscopy (TGRS) for stand-off detection of explosives and hazardous chemicals under realistic scenario are presented. Representative results drawn from the experimental study for detection of explosives and hazardous chemicals in simulated real field scenario are given.