Voltage-tunable multicolor electrochromic devices (ECDs) are fabricated based on flexible ion gels consisting of copolymers and ionic liquids as an electrolyte layer. Dimethyl ferrocene (dmFc) is incorporated into the gel, which serves as an anodic species. In this study, two electrochromic (EC) materials, monoheptyl viologen (MHV) and diheptyl viologen (DHV), are employed and show significantly different EC behavior despite the similar chemical structure. Both MHV- and DHV-containing ECDs are slightly yellowish in the bleached state, whereas the colored states are magenta and blue, respectively. All devices have good coloration efficiency of 87.5 cm/C (magenta) and 91.3 cm/C (blue). In addition, the required power of ∼248 μW/cm (magenta) and ∼72 μW/cm (blue) to maintain the colored state put the ion gel-based ECDs in a class of ultralow power consumption displays. On the basis of the distinct difference in the coloration voltage range between MHV and DHV, and the rubbery character of the gel, flexible ECDs showing multiple colors are demonstrated. These results imply that voltage-tunable multicolor ECDs based on the gel are attractive to functional electrochemical displays.
Dual-function electrochromic supercapacitors (ECSs) that indicate their real-time charge capacity in color are fabricated using tungsten trioxide (WO 3 ) and Lidoped ion gels containing hydroquinone (HQ). The ECSs can simultaneously serve as either electrochromic devices or supercapacitors. The coloration/bleaching and charging/ discharging characteristics are investigated between 0 and −1.5 V. At the optimal HQ concentration, large transmittance contrast (∼91%), high coloration efficiency (∼61.9 cm 2 /C), high areal capacitance (∼13.6 mF/cm 2 ), and good charging/discharging cyclic stability are achieved. Flexible ECSs are fabricated on plastic substrates by exploiting the elastic characteristics of the gel electrolytes, and they exhibit good bending durability. Moreover, practical feasibility is evaluated by demonstrating the use of the ECSs as an energy storage device and a power source.
Herein,
high-performance, reliable electrochromic supercapacitors (ECSs) are
proposed based on tungsten trioxide (WO3) and nickel oxide
(NiO) films. To maximize device performance and stability, the stoichiometric
balance between anode and cathode materials is controlled by carefully
adjusting the thickness of the anodic NiO film while fixing the thickness
of WO3 to ∼660 nm. Then, a small amount (≤10
mol %) of metal (e.g., copper) is doped into the NiO film, improving
the electrical conductivity and electrochemical activity. At a Cu
doping level of 7 mol %, the resulting ECS exhibited the highest performance,
including a high areal capacitance (∼14.9 mF/cm2), excellent coulombic efficiency (∼99%), wide operating temperature
range (0–80 °C), reliable operation with high charging/discharging
cyclic stability (>10,000 cycles), and good self-discharging durability.
Simultaneously, the change in transmittance of the device is well
synchronized with the galvanostatic charging/discharging curve by
which the real-time energy storage status is visually indicated. Furthermore,
the practical feasibility of the device is successfully demonstrated.
These results imply that the ECS fabricated in this work is a promising
potential energy storage platform and an attractive component for
future electronics.
Mesoporous metal oxides consisting of fully interconnected network structures with small pores (20–50 nm) have high surface areas and decreased ion intercalation distances, making them ideal for use in high-performance electrochromic supercapacitors (ECSs). Evaporation-induced self-assembly (EISA), which combines sol–gel chemistry and molecular self-assembly, is a powerful method for the fabrication of mesoporous metal oxides through a solution phase synthesis. Herein, we introduce ultrafast sub-1 s ECSs based on an amorphous mesoporous tungsten trioxide (WO3) that is prepared by EISA. Compared to that of a compact-WO3 film-based device, the performances of an ECS with mesoporous WO3 exhibits a large optical modulation (76% at 700 nm), ultrafast switching speeds (0.8 s for coloration and 0.4 s for bleaching), and a high areal capacitance (2.57 mF/cm2), even at a high current density (1.0 mA/cm2). In addition, the excellent device stability during the coloration/bleaching and charging/discharging cycles is observed under fast response conditions. Moreover, we fabricated a patterned mesoporous WO3 for ECS displays (ECSDs) via printing-assisted EISA (PEISA). The resulting ECSDs can be used as portable energy-storage devices, and their electrochromic reflective displays change color according to their stored energy level. The ECSDs in this work have enormous potential for use in next-generation smart windows for buildings and as portable energy storage displays.
Transparent displays have emerged as a class of cutting-edge
electronics.
Here, we propose user-customized, design-it-yourself (DIY) transparent
displays based on electrochromic (EC) ion gels including viologens.
To achieve multiple colors and enhance the functionality of EC displays
(ECDs), the incorporation of several EC chromophores is inevitable.
However, the issue related to the discrepancy of coloration voltages
is inherent due to the different electrochemical characteristics of
each material, causing unbalance of the color contrast. To overcome
this problem without significantly affecting the performance of ECDs,
we suggest a simple but effective strategy by adjusting the oxidation
activity of electrolyte-soluble anodic species (i.e., ferrocene (Fc)
derivatives) by modifying pendant groups. We systematically investigated
the effects of the employed Fc derivatives on the EC behaviors of
ECDs in terms of the coloration voltage, maximum transmittance contrast,
device dynamics, coloration efficiency, and operational stability.
We determine the conditions for implementing red-green-blue (RGB)
colors with comparable intensities at similar voltages. Last, we draw
images using RGB EC inks for conceptual demonstration of the DIY transparent
displays. The fabricated ECDs exhibit transparent bleached states
and user-customized images in the colored states. Overall, this result
implies that the extremely simple DIY ECDs, which do not require conventional
lithography or printing, have great potential as future transparent
displays that can be easily customized.
Energy‐storing functional photovoltaics, which can simultaneously harvest and store solar energy, are proposed as promising next‐generation multifunction energy systems. For the extension of conventional organic photovoltaics (OPVs), electrochromic supercapacitors (ECSs) are monolithically integrated with semitransparent (ST) quaternary blend‐based OPVs (ST Q‐OPVs) to achieve compact, energy‐efficient storage with great aesthetic appeal. In particular, ST Q‐OPVs with low‐power‐consumption ECSs allow full operation, even under low‐intensity irradiance, including artificial indoor light circumstances, and thereby exhibit potential for all‐day operating energy suppliers. The prepared ST energy‐storing functional photovoltaics also serve as a backup power source for external electronic equipment (e.g., light‐emitting diodes, and sensor nodes for Internet of Things) by consuming charged power. In addition to features that include unrestricted operation under any circumstances, color tunability, feasibility of designs with various shapes, rapid charging/discharging, and real‐time indication of stored energy levels, ST energy‐storing functional photovoltaics could potentially be applied in electronic devices such as advanced smart windows or portable smart electronics.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.