Flexible
and stretchable electrochromic supercapacitor systems
are widely considered as promising multifunctional energy storage
devices that eliminate the need for an external power source. Nevertheless,
the performance of conventional designs deteriorates significantly
as a result of electrode/electrolyte exposure to atmosphere as well
as mechanical deformations for the case of flexible systems. In this
study, we suggest an all-transparent stretchable electrochromic supercapacitor
device with ultrastable performance, which consists of Au/Ag core–shell
nanowire-embedded polydimethylsiloxane (PDMS), bistacked WO3 nanotube/PEDOT:PSS, and polyacrylamide (PAAm)-based hydrogel electrolyte.
Au/Ag core–shell nanowire-embedded PDMS integrated with PAAm-based
hydrogel electrolyte prevents Ag oxidation and dehydration while maintaining
ionic and electrical conductivity at high voltage even after 16 days
of exposure to ambient conditions and under application of mechanical
strains in both tensile and bending conditions. WO3 nanotube/PEDOT:PSS
bistacked active materials maintain high electrochemical–electrochromic
performance even under mechanical deformations. Maximum specific capacitance
of 471.0 F g–1 was obtained with a 92.9% capacity
retention even after 50 000 charge–discharge cycles.
In addition, high coloration efficiency of 83.9 cm2 C–1 was shown to be due to the dual coloration and pseudocapacitor
characteristics of the WO3 nanotube and PEDOT:PSS thin
layer.
Transpiration
is the process by which water is carried in plants from the roots
to the leaves where evaporation takes place. Here, we report a transpiration
driven electrokinetic power generator (TEPG) that exploits capillary
flow of water in an asymmetrically wetted cotton fabric coated with
carbon black. Accumulation of protons induced by the electrical double
layer formed at the solid (carbon black)/liquid (water) interface
gives rise to potential difference between the wet and dry sides.
The conductive carbon black coating channels electrical current driven
by the pseudostreaming mechanism. A TEPG of 90 mm × 30 mm ×
0.12 mm yields a maximum voltage of 0.53 V, maximum current of 3.91
μA, and maximum energy density of 1.14 mWh cm–3, depending on the loading of the carbon black. Multiple TEPGs generate
enough power to light up a light-emitting diode (20 mA × 2.2
V) or charge a 1 F supercapacitor.
The artificial hydrological cycle built by using deliquescent calcium chloride enables self-operation of a transpiration-driven electrokinetic power generator.
Nano-hydroelectric technology utilizes hydraulic flow through electronically conducting nanomaterials to generate electricity in a simple, renewable, ubiquitous, and environmentally friendly manner. Up to date, several designs of nano-hydroelectric devices have...
Carbon-nanotube (CNT)-based textile supercapacitors with MnO2 nanoparticles have excellent power and energy densities, but MnO2 nanoparticles can be delaminated during charge-discharge cycles, which results in significant degradation in capacitance. In this study, polypyrrole conductive polymer was coated on top of MnO2 nanoparticles that are deposited on CNT textile supercapacitor to prevent delamination of MnO2 nanoparticles. An increase of 38% in electrochemical energy capacity to 461 F/g was observed, while cyclic reliability also improved, as 93.8% of energy capacity was retained over 10 000 cycles. Energy density and power density were measured to be 31.1 Wh/kg and 22.1 kW/kg, respectively. An in situ electrochemical-mechanical study revealed that polypyrrole-MnO2-coated CNT textile supercapacitor can retain 98.5% of its initial energy capacity upon application of 21% tensile strain and showed no observable energy storage capacity change upon application of 13% bending strain. After imposing cyclic bending of 750 000 cycles, the capacitance was retained to 96.3%. Therefore, the results from this study confirmed for the first time that the polypyrrole-MnO2-coated CNT textile can reliably operate with high energy and power densities with in situ application of both tensile and bending strains.
Electrochromic devices have been widely adopted in energy saving applications by taking advantage of the electrode coloration, but it is critical to develop a new electrochromic device that can undergo smart coloration and can have a wide spectrum in transmittance in response to input light intensity while also functioning as a rechargeable energy storage system. In this study, a photoresponsive electrochromic supercapacitor based on cellulose-nanofiber/Ag-nanowire/reduced-graphene-oxide/WO -composite electrode that is capable of undergoing "smart" reversible coloration while simultaneously functioning as a reliable energy-storage device is developed. The fabricated device exhibits a high coloration efficiency of 64.8 cm C and electrochemical performance with specific capacitance of 406.0 F g , energy/power densities of 40.6-47.8 Wh kg and 6.8-16.9 kW kg . The electrochromic supercapacitor exhibits excellent cycle reliability, where 75.0% and 94.1% of its coloration efficiency and electrochemical performance is retained, respectively, beyond 10 000 charge-discharge cycles. Cyclic fatigue tests show that the developed device is mechanically durable and suitable for wearable electronics applications. The smart electrochromic supercapacitor system is then integrated with a solar sensor to enable photoresponsive coloration where the transmittance changes in response to varying light intensity.
Lithium-oxygen batteries have been considered as one of the most viable energy source options for electric vehicles due to their high energy density. However, they are still faced with technical challenges, such as low round-trip efficiency and short cycle life, which mainly originate from the cathode part of the battery. In this work, we designed a three-dimensional nanofibrous air electrode consisted of hierarchically structured carbon nanotube-bridged hollow FeO nanoparticles (H-FeO/CNT NFs). Composite nanofibers consisted of hollow FeO NPs anchored by multiple CNTs offered enhanced catalytic sites (interconnected hollow FeO NPs) and fast charge-transport highway (bridged CNTs) for facile formation and decomposition of LiO, leading to outstanding cell performance: (1) Swagelok cell exhibited highly reversible cycling characteristics for 250 cycles with a fixed capacity of 1000 mAh g at a current density of 500 mA g. (2) A module composed of two pouch-type cells stably powered an light-emitting diode lamp operated at 5.0 V.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.