Organo-silicon compounds S 0060Interaction of Heteroatom-Containing Propynals with S-, N-Binucleophiles. -Reactions of α-siliconand α-germanium-containing aldehydes (I) with primary amino compounds [(II), (V) and (VII)] proceed chemoselectively at the aldehyde group. In the case of 2-aminoethanethiol (II), the ratio of tautomers, 1,3-thiazolidine (III) and azomethine (IV), depends significantly on the nature of the heteroatom, the presence of a catalyst, and the use of microwave activation. -(DEMINA, M. M.; NOVOPASHIN, P. S.; KON'KOVA, T. V.; SARAPULOVA, G. I.; AFONIN, A. V.; MEDVEDEVA, A. S.; Chem. Heterocycl.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.