PbO-Sb(2)O(3)-B(2)O(3) glasses mixed with different concentrations of CoO (ranging from 0 to 2.0 mol%) were crystallized. The samples were characterized by x-ray diffraction, scanning electron microscopy and differential scanning calorimetric techniques. The x-ray diffraction and scanning electron microscopic studies have revealed the presence of CoSb(2)O(6), Co(2.33)Sb(0.67)O(4), Pb(5)Sb(2)O(8),Pb(3)(SbO(4))(2), PbB(4)O(7) and Co(3)O(4) crystalline phases in these samples. The DSC studies have indicated the spreading of the crystallization from the inside to the surface of the samples as the concentration of the crystallizing agent is increased. The IR and Raman spectroscopic studies have pointed out the existence of conventional BO(3), BO(4), SbO(4) and also Co(III)-O structural units in the glass ceramic samples. These studies have further indicated the decreasing concentration of symmetrical structural vibrational groups with increase in the concentration of CoO. The results of various studies, namely dielectric properties over a range of frequency and temperature, photo-induced birefringence, optical absorption, fluorescence and magnetic susceptibility at room temperature of PbO-Sb(2)O(3)-B(2)O(3):CoO glass ceramics, have also been reported. The variations observed as a function of the concentration of crystallizing agent in all these properties have been analyzed in the light of different oxidation states and environments of cobalt ions in the glass ceramic network.
The Indian mesosphere-stratosphere-troposphere (MST) radar observations during the passage of 37 convective systems are utilized to investigate the characteristics of vertical air velocity w in different convection categories (shallow, deep, and decaying) and also the differences in draft core statistics from the wet to dry spell. The radar and optical rain gauge measurements show pronounced differences in core statistics (in terms of their vertical structure, draft strength, size, number, and the elevation angle) and surface rainfall characteristics from the dry to wet spell. The shallow convective cores are preponderant in the dry spell. Composite w profiles, retrieved from all deep cases and also from individual convection cases, depict an upper-tropospheric peak in the wet spell and a bimodal distribution (peaks at 5 and 11-13 km) in the dry spell, illustrating that they are characteristic features of wet and dry spells. The average vertical extents of the cores are nearly equal (about 8 km) in both spells of the monsoon; however, the core-base (and top) altitudes are different. In both wet and dry spells, the composite w profile for all cores show similar vertical variation to that of for updraft cores, while the composite w for downdraft cores do not show much variation with altitude, indicating that the updraft cores dictate the vertical structure of composite w. The core size varies considerably (a factor of 2) with altitude in both spells of the monsoon. Although nearly equal in the lower troposphere in both phases of the monsoon, the core size is larger by 1-2 km in the dry spell in the middle and upper troposphere. Consistent with the longer lifetime (bigger core size) of cores in the dry spell, the cores are more inclined (with a mean elevation angle of 308) in the dry spell. The surface rainfall distribution is wider and has large number of intense rainfall rates in the wet spell. The mean rainfall rate for the wet spell is also larger by a factor of 2, consistent with earlier studies.
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